Enhanced Linear, Nonlinear Optical, and Modulus Dielectric Properties of Fluorescein Sodium Salt Dye Embedded Within Epoxy Resin Composite Materials for Renewable Energy Applications

IF 1.5 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Brazilian Journal of Physics Pub Date : 2025-01-10 DOI:10.1007/s13538-024-01691-9
Abdelfatteh Bouzidi, Soumaya Gouadria, Batool Bader Alyahya, Fatemah F. Al-Harbi
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Abstract

This research is aimed at investigating the potential of using fluorescent dyes, specifically fluorescein sodium salt dye (FSSD), embedded within epoxy resin (EP) as a material for luminescent solar concentrators (LSCs). LSCs are devices that capture and concentrate sunlight onto a smaller area, increasing the efficiency of solar cells. The study revealed a relationship between FSSD at different concentrations and EP molecules. The FSSD might be well-dispersed on a molecular level within the EP matrix. This homogeneous distribution is supported by the lack of distinct peaks in the XRD pattern, indicating the absence of any ordered crystal structure of FSSD within the composite. FSSD significantly influences the optical properties of the EP. It reduces light transmittance while increasing absorbance at specific wavelengths, which is crucial for efficient light capture in LSCs. The high polarizability of FSSD molecules and their random orientation can give rise to nonlinear optical phenomena. The enhanced light sensitivity of the FSSD@EP composite materials affects its nonlinear optical properties. These nonlinearities describe how the material’s response to light changes with increasing light intensity. The peak observed suggests a frequency range (105–107 rad/s) where this energy dissipation is most prominent. This points towards a relaxation process occurring within the material at those frequencies. As the frequency of the electric field increases, both the real part (M′) and the imaginary part (M″) of the complex modulus (M*) are expected to change in the FSSD@EP composite materials.

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可再生能源环氧树脂复合材料中荧光素钠盐染料增强线性、非线性光学和模介电性能
本研究旨在探讨将荧光染料,特别是荧光素钠盐染料(FSSD)嵌入环氧树脂(EP)中作为发光太阳能聚光器(LSCs)材料的潜力。LSCs是一种将太阳光捕获并集中到更小区域的设备,可以提高太阳能电池的效率。研究揭示了不同浓度的FSSD与EP分子之间的关系。FSSD可能在分子水平上分散在EP基质内。这种均匀分布得到了XRD图中缺乏明显峰的支持,表明复合材料中没有FSSD的任何有序晶体结构。FSSD对EP的光学特性影响很大。它降低了透光率,同时增加了特定波长的吸光度,这对LSCs的高效光捕获至关重要。FSSD分子的高极化率及其取向的随机性会引起非线性光学现象。FSSD@EP复合材料的光敏性增强影响了其非线性光学性能。这些非线性描述了材料对光的响应如何随着光强度的增加而变化。观测到的峰值表明,在105-107 rad/s的频率范围内,能量耗散最为突出。这指向了在这些频率上发生在材料内部的松弛过程。随着电场频率的增加,预计FSSD@EP复合材料的复模量(M*)的实部(M′)和虚部(M″)都会发生变化。
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来源期刊
Brazilian Journal of Physics
Brazilian Journal of Physics 物理-物理:综合
CiteScore
2.50
自引率
6.20%
发文量
189
审稿时长
6.0 months
期刊介绍: The Brazilian Journal of Physics is a peer-reviewed international journal published by the Brazilian Physical Society (SBF). The journal publishes new and original research results from all areas of physics, obtained in Brazil and from anywhere else in the world. Contents include theoretical, practical and experimental papers as well as high-quality review papers. Submissions should follow the generally accepted structure for journal articles with basic elements: title, abstract, introduction, results, conclusions, and references.
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