Immobilization and solid reaction of adsorbed metal ions using heat treatment of synthesized Na-P1 type zeolite from coal fly ash

IF 1.9 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Bulletin of Materials Science Pub Date : 2025-01-11 DOI:10.1007/s12034-024-03371-5
Hiromichi Aono, Ami Takahashi, Takumi Miyamoto, Yoshiteru Itagaki
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Abstract

The Na-P1 type zeolites were synthesized using coal fly ash (FA-Na-P1) and also using chemical reagents (CA-Na-P1) for comparison. Both Na-P1 type zeolites showed a superior adsorption ability for the non-radioactive metal ions of Cs, Sr, Mn, Zn, Co, or Fe, assuming radioisotopes with relatively long half-lives. These zeolites were heat-treated for the immobilization of the adsorbed metal ions in the decomposed zeolite. The elution ratio of the metal ions in the deionized water and seawater for 14 days showed a low elution when the sample was heated at 1000°C and higher temperature for both zeolites. In particular, the elution of the 1100°C heated sample for the zeolite from fly ash significantly decreased compared with that from the chemical reagents. The reaction between the adsorbed cation and zeolite was confirmed to form polymetallic oxide. The formation of the reacted oxide phase suppressed the elution ratio for the FA-Na-P1 zeolite.

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粉煤灰合成Na-P1型沸石热处理对吸附金属离子的固定化和固相反应
以粉煤灰(FA-Na-P1)和化学试剂(CA-Na-P1)为原料合成Na-P1型沸石。两种Na-P1型沸石对Cs、Sr、Mn、Zn、Co、Fe等非放射性金属离子具有较好的吸附能力,假设这些放射性同位素具有较长的半衰期。对这些沸石进行热处理,将吸附的金属离子固定在分解后的沸石中。当样品在1000℃和更高温度下加热时,金属离子在去离子水和海水中洗脱率为低,两种沸石加热14天。特别是,1100℃加热后粉煤灰沸石样品的洗脱量明显低于化学试剂。吸附后的阳离子与沸石反应生成多金属氧化物。反应氧化相的形成抑制了FA-Na-P1沸石的洗脱比。
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来源期刊
Bulletin of Materials Science
Bulletin of Materials Science 工程技术-材料科学:综合
CiteScore
3.40
自引率
5.60%
发文量
209
审稿时长
11.5 months
期刊介绍: The Bulletin of Materials Science is a bi-monthly journal being published by the Indian Academy of Sciences in collaboration with the Materials Research Society of India and the Indian National Science Academy. The journal publishes original research articles, review articles and rapid communications in all areas of materials science. The journal also publishes from time to time important Conference Symposia/ Proceedings which are of interest to materials scientists. It has an International Advisory Editorial Board and an Editorial Committee. The Bulletin accords high importance to the quality of articles published and to keep at a minimum the processing time of papers submitted for publication.
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