Simulation of solar photocatalytic reactor with immobilized photocatalyst for degradation of pharmaceutical pollutants

IF 5.8 3区 环境科学与生态学 0 ENVIRONMENTAL SCIENCES Environmental Science and Pollution Research Pub Date : 2025-01-09 DOI:10.1007/s11356-024-35869-0
Parinaz Deymi, Hajir Karimi, Hakimeh Sharififard, Fatemeh Salehi
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Abstract

This study focuses on the simulation of a solar photocatalytic reactor with linear parabolic reflectors and continuous fluid flow. The simulation approach was initially validated against experimental data reported by Miranda-Garcia et al. Catal Today 151:107-113 (2010), yielding a high degree of accuracy of approximately 0.99%. In this article, the effect of light intensity, Reynolds number, and fluid residence time on the performance of a photoreactor system using titanium dioxide catalyst and ibuprofen pollutant has been investigated. The results show that the intensity of light intensity has an effect of up to 29% on the decomposition of pollutant. With the increase of radiation intensity, the removal of pollutants reached from 85.5% to 99.46%. It has been demonstrated that higher flow turbulence significantly impacts removal efficiency, achieving rates of up to 71%. Moreover, enhancing the fluid’s residence time through implementing a recirculating flow within the photoreactor has resulted in a 13% enhancement in removal efficiency. These results can be an important guide for optimizing the design of photocatalytic reactors. By adjusting the examined parameters, it is possible to obtain a higher efficiency in the removal of pollutants, which will be very effective in the scaling and industrial design of solar reactors.

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固定化光催化剂太阳能光催化反应器降解药物污染物的模拟研究。
本文研究了具有线性抛物面反射镜和连续流体流动的太阳能光催化反应器的模拟。模拟方法最初通过Miranda-Garcia等人报告的实验数据进行了验证。《今日加泰罗尼亚》151:107-113(2010),准确度约为0.99%。本文研究了光强、雷诺数和流体停留时间对二氧化钛催化剂和布洛芬污染物光反应器系统性能的影响。结果表明,光照强度对污染物分解的影响可达29%。随着辐射强度的增加,污染物去除率从85.5%提高到99.46%。研究表明,较高的湍流度会显著影响去除效率,去除率可达71%。此外,通过在光反应器内实现再循环流动来延长流体的停留时间,使去除效率提高了13%。这些结果对光催化反应器的优化设计具有重要的指导意义。通过调整所研究的参数,可以获得更高的污染物去除效率,这将在太阳能反应器的规模化和工业设计中非常有效。
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来源期刊
CiteScore
8.70
自引率
17.20%
发文量
6549
审稿时长
3.8 months
期刊介绍: Environmental Science and Pollution Research (ESPR) serves the international community in all areas of Environmental Science and related subjects with emphasis on chemical compounds. This includes: - Terrestrial Biology and Ecology - Aquatic Biology and Ecology - Atmospheric Chemistry - Environmental Microbiology/Biobased Energy Sources - Phytoremediation and Ecosystem Restoration - Environmental Analyses and Monitoring - Assessment of Risks and Interactions of Pollutants in the Environment - Conservation Biology and Sustainable Agriculture - Impact of Chemicals/Pollutants on Human and Animal Health It reports from a broad interdisciplinary outlook.
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