The Wear-Resistant Self-Cleaning Interface Prepared with Silica Sol Through Sol-Gel Method

IF 0.8 4区 材料科学 Q4 MATERIALS SCIENCE, CERAMICS Glass Physics and Chemistry Pub Date : 2025-01-13 DOI:10.1134/S1087659624600029
Jiefang Li, Que Kong, Dan Zhang, Zhiguang Li
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Abstract

Self-cleaning materials played an important role in our daily life, but there remained some critical challenges such as complex fabrications, non-transparency, and poor long-term stability, which limited their applications. In this paper, acid-base silica sol and alkali-based silica sol were prepared by sol-gel method, with ethyl orthosilicate as the precursor. The two silica sols were mixed by different proportions. The mixed silica sol was evenly coated on the surface of the pretreated glass slide, and then modified by the low surface energy substance HDTMS and QX-18 fluorocarbon nanocoating, and finally prepared a hydrophobic and wear-resistant transparent coating. The surface topography of the coating was analyzed, and its acid and alkali resistance, wear resistance, self-cleaning performance and other properties were tested. The results showed that the optimal volume ratio of acid-base mixed sol was acid silica sol : alkaline silica sol = 3 : 7. The hydrophobic coating had good wear resistance, transparency, self-cleaning and acid resistance, but poor alkaline resistance.

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溶胶-凝胶法制备硅溶胶耐磨自清洁界面
自清洁材料在我们的日常生活中发挥着重要的作用,但仍存在一些关键的挑战,如制造复杂、不透明、长期稳定性差等,限制了其应用。本文以正硅酸乙酯为前驱体,采用溶胶-凝胶法制备了酸碱硅溶胶和碱基硅溶胶。将两种硅溶胶按不同比例混合。将混合硅溶胶均匀涂覆在预处理后的玻片表面,再用低表面能物质HDTMS和QX-18氟碳纳米涂层进行改性,最终制备出疏水耐磨的透明涂层。对涂层的表面形貌进行了分析,并对其耐酸、耐碱、耐磨性、自清洁性能等性能进行了测试。结果表明,酸碱混合溶胶的最佳体积比为酸性硅溶胶:碱性硅溶胶= 3:7。疏水涂层具有良好的耐磨性、透明性、自洁性和耐酸性,但耐碱性较差。
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来源期刊
Glass Physics and Chemistry
Glass Physics and Chemistry 工程技术-材料科学:硅酸盐
CiteScore
1.20
自引率
14.30%
发文量
46
审稿时长
6-12 weeks
期刊介绍: Glass Physics and Chemistry presents results of research on the inorganic and physical chemistry of glass, ceramics, nanoparticles, nanocomposites, and high-temperature oxides and coatings. The journal welcomes manuscripts from all countries in the English or Russian language.
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