Padma Priya V. R., Sugapriya S., Antony Haritha Mercy A., Natarajan K., Ramesh Kataria, Ganesh Chandra Nandi
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引用次数: 0
Abstract
Herein, we present a metal-/catalyst-free, novel approach for S-sulfoximination of sulfenamide. The electrooxidative reactions of sulfenamides and sulfoximines are fast, high-yielding, atom-economical (99.5%), broad-substrate-tolerant, and free from supporting electrolytes. The protocol is ecofriendly and shows wider substrate tolerance than previous reports. The drug-attached sulfenamide (levetiracetam) and sulfoximine (albendazole) also undergo the reaction efficiently. A possible mechanistic pathway is proposed. Fascinatingly, the target products are also obtained via a photochemical approach in the presence of photocatalyst eosin Y.
期刊介绍：
ACS Sustainable Chemistry & Engineering is a prestigious weekly peer-reviewed scientific journal published by the American Chemical Society. Dedicated to advancing the principles of green chemistry and green engineering, it covers a wide array of research topics including green chemistry, green engineering, biomass, alternative energy, and life cycle assessment.
The journal welcomes submissions in various formats, including Letters, Articles, Features, and Perspectives (Reviews), that address the challenges of sustainability in the chemical enterprise and contribute to the advancement of sustainable practices. Join us in shaping the future of sustainable chemistry and engineering.
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