Stable Luminescent Diradicals: The Emergence and Potential Applications

IF 16.9 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Angewandte Chemie International Edition Pub Date : 2025-01-16 DOI:10.1002/anie.202423470
Yujie Zhu, Zihao Zhu, Saixue Wang, Prof. Dr. Qiming Peng, Prof. Dr. Alim Abdurahman
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Abstract

Stable luminescent diradicals, characterized by the presence of two unpaired electrons, exhibit unique photophysical properties that are sensitive to external stimuli such as temperature, magnetic fields, and microwaves. This sensitivity allows the manipulation of their spin states and luminescence, setting them apart from traditional closed-shell luminescent molecules and luminescent monoradicals. As a result, luminescent diradicals are emerging as promising candidates for a variety of applications. This minireview discusses recent advances in the design and synthesis of luminescent diradicals, explores their photophysical properties and potential applications. It also examines the challenges and prospects in the development of these materials, shedding light on their potential to drive technological innovation.

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稳定发光双自由基的产生及其潜在应用
稳定的发光双自由基,以两个未配对电子的存在为特征,表现出独特的光物理性质,对温度、磁场和微波等外部刺激敏感。这种灵敏度允许操纵它们的自旋状态和发光,使它们与传统的闭壳发光分子和发光单基分子区别开来。因此,发光二自由基正在成为各种应用的有前途的候选者。本文综述了发光二自由基的设计和合成的最新进展,探讨了它们的光物理性质和潜在的应用前景。它还研究了这些材料发展中的挑战和前景,揭示了它们推动技术创新的潜力。
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来源期刊
CiteScore
26.60
自引率
6.60%
发文量
3549
审稿时长
1.5 months
期刊介绍: Angewandte Chemie, a journal of the German Chemical Society (GDCh), maintains a leading position among scholarly journals in general chemistry with an impressive Impact Factor of 16.6 (2022 Journal Citation Reports, Clarivate, 2023). Published weekly in a reader-friendly format, it features new articles almost every day. Established in 1887, Angewandte Chemie is a prominent chemistry journal, offering a dynamic blend of Review-type articles, Highlights, Communications, and Research Articles on a weekly basis, making it unique in the field.
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