Nonlocal Effects in Plasmons of Grooved Gold Cylindrical Structures Based on Modified Hydrodynamic Theory

IF 3.3 3区 化学 Q2 CHEMISTRY, PHYSICAL The Journal of Physical Chemistry C Pub Date : 2025-01-16 DOI:10.1021/acs.jpcc.4c07962
Xiuwen Xi, Zheng Wang, Heng Zhang, Jianguo Wan, Chuanfu Huang
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Abstract

This work explores the nonlocal behavior of the optical response of infinitely long gold (Au) cylindrical nanostructures (ILANs) with controllable grooves. By varying three parameters, such as the number of grooves, the groove width, and the material of the connector, the systematic calculations of the plasmon resonance peaks of ILANs are performed under classical local theory and modified hydrodynamic (nonlocal) theory. We find that the properties of metallic nanostructures calculated using local theory are not significantly dependent on changes in their size, shape, or environment. However, under nonlocal theory, we observe that the optical properties of ILANs is highly reliant on these three variables. Compare to the classical local theory, we successfully apply the more accurate modified hydrodynamic theory to complex nanometallic structures, which lays a foundation for the theory and design of optical devices.

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基于修正流体力学理论的沟槽金圆柱结构等离激元的非局部效应
本研究探讨了具有可控凹槽的无限长金(Au)圆柱形纳米结构(ILANs)的光学响应的非局域行为。通过改变沟槽数、沟槽宽度和连接器材料三个参数,在经典局域理论和修正流体力学(非局域)理论下系统地计算了等离子体共振峰。我们发现,使用局部理论计算的金属纳米结构的性质并不明显依赖于它们的大小、形状或环境的变化。然而,在非局域理论下,我们观察到ILANs的光学性质高度依赖于这三个变量。与经典的局部理论相比,我们成功地将更精确的修正流体力学理论应用于复杂的纳米金属结构,为光学器件的理论和设计奠定了基础。
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来源期刊
The Journal of Physical Chemistry C
The Journal of Physical Chemistry C 化学-材料科学:综合
CiteScore
6.50
自引率
8.10%
发文量
2047
审稿时长
1.8 months
期刊介绍: The Journal of Physical Chemistry A/B/C is devoted to reporting new and original experimental and theoretical basic research of interest to physical chemists, biophysical chemists, and chemical physicists.
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