{"title":"Nonlocal Effects in Plasmons of Grooved Gold Cylindrical Structures Based on Modified Hydrodynamic Theory","authors":"Xiuwen Xi, Zheng Wang, Heng Zhang, Jianguo Wan, Chuanfu Huang","doi":"10.1021/acs.jpcc.4c07962","DOIUrl":null,"url":null,"abstract":"This work explores the nonlocal behavior of the optical response of infinitely long gold (Au) cylindrical nanostructures (ILANs) with controllable grooves. By varying three parameters, such as the number of grooves, the groove width, and the material of the connector, the systematic calculations of the plasmon resonance peaks of ILANs are performed under classical local theory and modified hydrodynamic (nonlocal) theory. We find that the properties of metallic nanostructures calculated using local theory are not significantly dependent on changes in their size, shape, or environment. However, under nonlocal theory, we observe that the optical properties of ILANs is highly reliant on these three variables. Compare to the classical local theory, we successfully apply the more accurate modified hydrodynamic theory to complex nanometallic structures, which lays a foundation for the theory and design of optical devices.","PeriodicalId":61,"journal":{"name":"The Journal of Physical Chemistry C","volume":"118 1","pages":""},"PeriodicalIF":3.3000,"publicationDate":"2025-01-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"The Journal of Physical Chemistry C","FirstCategoryId":"1","ListUrlMain":"https://doi.org/10.1021/acs.jpcc.4c07962","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
This work explores the nonlocal behavior of the optical response of infinitely long gold (Au) cylindrical nanostructures (ILANs) with controllable grooves. By varying three parameters, such as the number of grooves, the groove width, and the material of the connector, the systematic calculations of the plasmon resonance peaks of ILANs are performed under classical local theory and modified hydrodynamic (nonlocal) theory. We find that the properties of metallic nanostructures calculated using local theory are not significantly dependent on changes in their size, shape, or environment. However, under nonlocal theory, we observe that the optical properties of ILANs is highly reliant on these three variables. Compare to the classical local theory, we successfully apply the more accurate modified hydrodynamic theory to complex nanometallic structures, which lays a foundation for the theory and design of optical devices.
期刊介绍:
The Journal of Physical Chemistry A/B/C is devoted to reporting new and original experimental and theoretical basic research of interest to physical chemists, biophysical chemists, and chemical physicists.