Brownian bridges for contained random walks

IF 3.5 3区 工程技术 Q2 ENGINEERING, CHEMICAL AIChE Journal Pub Date : 2025-01-20 DOI:10.1002/aic.18658
George Curtis, Doraiswami Ramkrishna, Vivek Narsimhan
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We show that such trajectories can be efficiently generated through the use of a Brownian Bridge, derived via the solution to the Backward Fokker–Planck (BFP) equation. Using linear operator techniques, we place the BFP operator in self-adjoint form and show that in the asymptotic limit <span data-altimg=\"/cms/asset/128708a3-6ffd-4c86-b14d-78bdfa6190b3/aic18658-math-0002.png\"></span><mjx-container ctxtmenu_counter=\"251\" ctxtmenu_oldtabindex=\"1\" jax=\"CHTML\" role=\"application\" sre-explorer- style=\"font-size: 103%; position: relative;\" tabindex=\"0\"><mjx-math aria-hidden=\"true\" location=\"graphic/aic18658-math-0002.png\"><mjx-semantics><mjx-mrow data-semantic-children=\"0,2\" data-semantic-content=\"1\" data-semantic- data-semantic-role=\"inequality\" data-semantic-speech=\"upper T much greater than 1\" data-semantic-type=\"relseq\"><mjx-mi data-semantic-annotation=\"clearspeak:simple\" data-semantic-font=\"italic\" data-semantic- data-semantic-parent=\"3\" data-semantic-role=\"latinletter\" data-semantic-type=\"identifier\"><mjx-c></mjx-c></mjx-mi><mjx-mo data-semantic- data-semantic-operator=\"relseq,≫\" data-semantic-parent=\"3\" data-semantic-role=\"inequality\" data-semantic-type=\"relation\" rspace=\"5\" space=\"5\"><mjx-c></mjx-c></mjx-mo><mjx-mn data-semantic-annotation=\"clearspeak:simple\" data-semantic-font=\"normal\" data-semantic- data-semantic-parent=\"3\" data-semantic-role=\"integer\" data-semantic-type=\"number\"><mjx-c></mjx-c></mjx-mn></mjx-mrow></mjx-semantics></mjx-math><mjx-assistive-mml display=\"inline\" unselectable=\"on\"><math altimg=\"urn:x-wiley:00011541:media:aic18658:aic18658-math-0002\" display=\"inline\" location=\"graphic/aic18658-math-0002.png\" overflow=\"scroll\" xmlns=\"http://www.w3.org/1998/Math/MathML\"><semantics><mrow data-semantic-=\"\" data-semantic-children=\"0,2\" data-semantic-content=\"1\" data-semantic-role=\"inequality\" data-semantic-speech=\"upper T much greater than 1\" data-semantic-type=\"relseq\"><mi data-semantic-=\"\" data-semantic-annotation=\"clearspeak:simple\" data-semantic-font=\"italic\" data-semantic-parent=\"3\" data-semantic-role=\"latinletter\" data-semantic-type=\"identifier\">T</mi><mo data-semantic-=\"\" data-semantic-operator=\"relseq,≫\" data-semantic-parent=\"3\" data-semantic-role=\"inequality\" data-semantic-type=\"relation\">≫</mo><mn data-semantic-=\"\" data-semantic-annotation=\"clearspeak:simple\" data-semantic-font=\"normal\" data-semantic-parent=\"3\" data-semantic-role=\"integer\" data-semantic-type=\"number\">1</mn></mrow>$$ T\\gg 1 $$</annotation></semantics></math></mjx-assistive-mml></mjx-container>, the set of paths contained in a specified region is equivalent to paths on a modified potential energy landscape that is related to the dominant eigenfunction of the self-adjoint BFP operator. We demonstrate this idea on several example problems, one of which is the Graetz problem, where one is interested in the survival time of a particle diffusing in tube flow.","PeriodicalId":120,"journal":{"name":"AIChE Journal","volume":"5 1","pages":""},"PeriodicalIF":3.5000,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"AIChE Journal","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1002/aic.18658","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
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Abstract

Using linear operator techniques, we demonstrate an efficient method for investigating rare events in stochastic processes. Specifically, we examine contained trajectories, which are continuous random walks that only leave a specified region of phase space after a set period of time T$$ T $$. We show that such trajectories can be efficiently generated through the use of a Brownian Bridge, derived via the solution to the Backward Fokker–Planck (BFP) equation. Using linear operator techniques, we place the BFP operator in self-adjoint form and show that in the asymptotic limit T1$$ T\gg 1 $$, the set of paths contained in a specified region is equivalent to paths on a modified potential energy landscape that is related to the dominant eigenfunction of the self-adjoint BFP operator. We demonstrate this idea on several example problems, one of which is the Graetz problem, where one is interested in the survival time of a particle diffusing in tube flow.
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包含随机漫步的布朗桥
利用线性算子技术,我们展示了一种研究随机过程中罕见事件的有效方法。具体来说,我们检查包含的轨迹,它是连续的随机行走,只在一段时间T $$ T $$后离开相空间的指定区域。我们证明了这样的轨迹可以通过使用布朗桥有效地生成,该桥是由后向福克-普朗克(BFP)方程的解导出的。利用线性算子技术,我们将BFP算子置于自伴随形式,并证明了在渐近极限T≠1 $$ T\gg 1 $$下,特定区域内的路径集合等价于与自伴随BFP算子的优势特征函数相关的修正势能景观上的路径。我们在几个例子问题上证明了这个想法,其中一个是Graetz问题,人们对粒子在管流中扩散的生存时间感兴趣。
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来源期刊
AIChE Journal
AIChE Journal 工程技术-工程:化工
CiteScore
7.10
自引率
10.80%
发文量
411
审稿时长
3.6 months
期刊介绍: The AIChE Journal is the premier research monthly in chemical engineering and related fields. This peer-reviewed and broad-based journal reports on the most important and latest technological advances in core areas of chemical engineering as well as in other relevant engineering disciplines. To keep abreast with the progressive outlook of the profession, the Journal has been expanding the scope of its editorial contents to include such fast developing areas as biotechnology, electrochemical engineering, and environmental engineering. The AIChE Journal is indeed the global communications vehicle for the world-renowned researchers to exchange top-notch research findings with one another. Subscribing to the AIChE Journal is like having immediate access to nine topical journals in the field. Articles are categorized according to the following topical areas: Biomolecular Engineering, Bioengineering, Biochemicals, Biofuels, and Food Inorganic Materials: Synthesis and Processing Particle Technology and Fluidization Process Systems Engineering Reaction Engineering, Kinetics and Catalysis Separations: Materials, Devices and Processes Soft Materials: Synthesis, Processing and Products Thermodynamics and Molecular-Scale Phenomena Transport Phenomena and Fluid Mechanics.
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