Surface-reconstructed FeOOH@CoFeOS/NF architectures: leveraging nano-layered stacking for accelerated oxygen evolution kinetics†

IF 2.5 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY New Journal of Chemistry Pub Date : 2025-01-03 DOI:10.1039/D4NJ04690K
Xuelei Wang, Xiang Li, Baohua Li, Wenchun Wang, Shizhen Bai, Shifeng Zai, Zhenhai Ni and Chao Meng
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Abstract

A high-efficiency oxygen-evolution reaction (OER) catalyst (FeOOH@CoFeOS/NF) was synthesized on nickel foam (NF), utilizing an intermolecular synergistic effect. The optimized FeOOH@CoFeOS/NF catalyst demonstrated outstanding alkaline OER performance, exhibiting a low overpotential of 212 mV at 10 mA cm−2 (η10) (25 °C), along with a small Tafel slope of 62.8 mV dec−1. Notably, FeOOH@CoFeOS/NF maintained its stability in 1.0 M KOH for 38 h. The achieved results surpassed those of the majority of transition metal oxide sulfide catalysts. This research contributes a valuable methodology for leveraging intermolecular cooperative effects and the development of high-performance OER electrocatalysts.

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表面重建FeOOH@CoFeOS/NF结构:利用纳米层状堆叠加速析氧动力学†
利用分子间协同作用,在泡沫镍(NF)上合成了高效析氧反应(OER)催化剂(FeOOH@CoFeOS/NF)。优化后的FeOOH@CoFeOS/NF催化剂具有良好的碱性OER性能,在10 mA cm−2 (η10)(25°C)下的过电位为212 mV,塔菲尔斜率为62.8 mV dec−1。值得注意的是,FeOOH@CoFeOS/NF在1.0 M KOH中保持了38 h的稳定性,所取得的结果超过了大多数过渡金属氧化物硫化物催化剂。本研究为利用分子间协同效应和开发高性能OER电催化剂提供了有价值的方法。
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来源期刊
New Journal of Chemistry
New Journal of Chemistry 化学-化学综合
CiteScore
5.30
自引率
6.10%
发文量
1832
审稿时长
2 months
期刊介绍: A journal for new directions in chemistry
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