Influence of Interfacial Phenomena on the Behavior of Condensate Gas Phase in Low-Permeability and Dense Porous Media

IF 0.7 4区 化学 Q4 CHEMISTRY, PHYSICAL Russian Journal of Physical Chemistry A Pub Date : 2025-01-17 DOI:10.1134/S0036024424702261
Hanmin Tu, Shiyong Hu, Ping Guo, Xinyu Wang, Zhongshun Min, Haiyan He
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Abstract

Low-permeability and tight condensate gas reservoirs are critically important in gas field development due to their substantial reserves and high economic value. However, retrograde condensation significantly affects oil and gas productivity during development. Understanding the impacts of interfacial phenomena in porous media is crucial for enhancing recovery rates of gas and condensate oil. This study integrates the capillary effect and adsorption into a phase equilibrium model, based on the Peng–Robinson equation of state (PR-EOS), to account for interfacial phenomena. The results indicate that the interfacial phenomena significantly impact the phase behavior of condensate gas. Interfacial effects increased the dew point pressure (Pd) by 0.47 MPa and the maximum condensate oil saturation (Somax) by 3.95%. Capillary pressure primarily affects fluid phase behavior and mobility, while adsorption influences fluid composition and interfacial tension. When the capillary radius (r) is less than 100 nm, Pd increases rapidly with decreasing r. At a pore radius of 30 nm, Pd and Somax increased by 1.06 MPa and 5.23%, respectively. Higher heavy component content in the fluids enhances capillary pressure and desorption, leading to increased Pd and Somax. Ignoring adsorption and capillary effects can adversely affect reservoir development. The established numerical model considering complex adsorption characteristics and capillary pressure is crucial for understanding phase behavior in high-temperature, high-pressure porous media and optimizing development strategies for condensate gas reservoirs.

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低渗致密多孔介质中界面现象对凝析气相行为的影响
低渗透致密凝析气藏储量大,经济价值高,在气田开发中具有十分重要的地位。然而,在开发过程中,逆行凝析会严重影响油气产能。了解多孔介质中界面现象的影响对提高气凝析油采收率至关重要。本研究基于Peng-Robinson状态方程(PR-EOS),将毛细管效应和吸附作用整合到相平衡模型中,以解释界面现象。结果表明,界面现象对凝析气相行为有显著影响。界面效应使露点压力(Pd)提高0.47 MPa,最大凝析油饱和度(Somax)提高3.95%。毛细管压力主要影响流体相行为和流动性,而吸附作用主要影响流体组成和界面张力。当孔半径r < 100 nm时,Pd随r的减小而迅速增加,孔半径为30 nm时,Pd和Somax分别增加1.06 MPa和5.23%。流体中较高的重质组分含量增加了毛细管压力和解吸作用,导致Pd和Somax增加。忽略吸附和毛细效应会对储层开发产生不利影响。建立的考虑复杂吸附特性和毛管压力的数值模型对于理解高温高压多孔介质中相行为和优化凝析气藏开发策略具有重要意义。
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来源期刊
CiteScore
1.20
自引率
14.30%
发文量
376
审稿时长
5.1 months
期刊介绍: Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world. Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.
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