Effects on curing characteristics and physical properties of hybrid carbon black /feldspar filled several types of rubbers for selection of rubber applications

IF 1.2 4区 化学 Q4 POLYMER SCIENCE Journal of Rubber Research Pub Date : 2024-12-27 DOI:10.1007/s42464-024-00291-1
Neettha Nai Sem, Norfatirah Muhamad Sarih, Shamin Aida Mohd Din, Azura A. Rashid
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Abstract

Carbon black (CB) and silica are conventional fillers used extensively in the tyre industry worldwide. Due to its affordability and sustainability, feldspar can be utilised as an alternative to traditional fillers in the production of tyres. Styrene-butadiene rubber (SBR) filled with feldspar and CB (SBR/CB-Feldspar) has been used in this study to assess feldspar's potential as a reinforcement filler in tyre tread applications. CB:Silica was compared to CB:Feldspar at a similar ratio to determine the ideal hybrid filler system. For both control and hybrid compounds, this work observed the impacts of different sulphur vulcanisation systems, including conventional vulcanisation (CV), efficient vulcanisation (EV), and semi-efficient vulcanisation (semi-EV). The control compound, which contains 40 parts per hundred rubber (phr) of CB, is based on the composition of hybrid compounds, which have CB:Feldspar filler ratios of 30:10, 20:20, and 10:30. The findings demonstrate that the semi-EV system reduces the SBR-Feldspar compound’s scorch and cure times. The hybrid compound's curing characteristics and physical properties, such as tensile strength, hardness, rebound resilience, and abrasion resistance, have been enhanced using SBR/CB-Feldspar with the maximum CB content (30 phr). Moreover, further research on optimised hybrid CB:Feldspar composition with various rubbers has been conducted to examine the effects on curing characteristics and mechanical properties of hybrid fillers with the rubbers, including Natural rubber (NR), Ethylene Propylene Diene Rubber (EPDM), Chloroprene Rubber (CR), and Nitrile Rubber (NBR). These results conclusively establish the potential value of feldspar, which can function as a softener, extender, and can be considered a semi-reinforcing filler for various rubber applications.

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对炭黑/长石杂化填充几种橡胶的固化特性和物理性能的影响,为橡胶应用的选择提供依据
炭黑(CB)和二氧化硅是轮胎工业中广泛使用的常规填料。由于其可负担性和可持续性,长石可以用作轮胎生产中传统填料的替代品。采用长石-丁二烯橡胶(SBR/CB-长石)填充长石和丁二烯橡胶(SBR/CB-长石)来评估长石作为轮胎胎面补强填料的潜力。将炭黑:二氧化硅与炭黑:长石以相似的比例进行比较,以确定理想的混合填料体系。对于对照和杂化化合物,本研究观察了不同硫化体系的影响,包括常规硫化(CV)、高效硫化(EV)和半高效硫化(semi-EV)。对照化合物含有百份橡胶(phr)的40份CB,其基础是杂化化合物的组成,其中CB:长石填充比为30:10,20:20和10:30。研究结果表明,半ev体系减少了sbr -长石化合物的烧焦和固化时间。采用最大CB含量(30 phr)的SBR/CB-长石,提高了复合材料的固化性能和抗拉强度、硬度、回弹回弹性、耐磨性等物理性能。此外,还进一步研究了优化的氯化碳:长石与各种橡胶的杂化组合,考察了与天然橡胶(NR)、乙丙橡胶(EPDM)、氯丁橡胶(CR)和丁腈橡胶(NBR)等橡胶的杂化填料对固化特性和机械性能的影响。这些结果最终确定了长石的潜在价值,它可以作为柔软剂、膨胀剂,可以考虑作为各种橡胶应用的半增强填料。
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来源期刊
Journal of Rubber Research
Journal of Rubber Research 化学-高分子科学
自引率
15.40%
发文量
46
审稿时长
3 months
期刊介绍: The Journal of Rubber Research is devoted to both natural and synthetic rubbers, as well as to related disciplines. The scope of the journal encompasses all aspects of rubber from the core disciplines of biology, physics and chemistry, as well as economics. As a specialised field, rubber science includes within its niche a vast potential of innovative and value-added research areas yet to be explored. This peer reviewed publication focuses on the results of active experimental research and authoritative reviews on all aspects of rubber science. The Journal of Rubber Research welcomes research on: the upstream, including crop management, crop improvement and protection, and biotechnology; the midstream, including processing and effluent management; the downstream, including rubber engineering and product design, advanced rubber technology, latex science and technology, and chemistry and materials exploratory; economics, including the economics of rubber production, consumption, and market analysis. The Journal of Rubber Research serves to build a collective knowledge base while communicating information and validating the quality of research within the discipline, and bringing together work from experts in rubber science and related disciplines. Scientists in both academia and industry involved in researching and working with all aspects of rubber will find this journal to be both source of information and a gateway for their own publications.
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