Molybdenum catalyzed homogeneous hydrogenation reaction: Recent innovations in catalysts design, modes of activation and reaction mechanisms

IF 6.5 1区化学 Q2 CHEMISTRY, PHYSICAL Journal of Catalysis Pub Date : 2025-01-27 DOI:10.1016/j.jcat.2025.115984

Shu-Fen Hou, Ailing Zhang, Chunling Xin, Mengyuan Zhang

引用次数: 0

Abstract

Transition metal-catalyzed reactions are increasingly recognized as essential in synthetic organic chemistry, due to their occurrence under relatively mild conditions. In this regard, molybdenum (Mo) complexes are considered as an attractive class of catalysts because of their rich redox activities, abundance and low toxicity. Molybdenum catalysis has seen significant advancements in recent years, leading to a diverse range of useful transformations for the activation of E-H bonds. Recent developments in Mo catalysis focusing on the hydrogenation reaction are highlighted in this perspective. Additionally, the synthesis of Mo-based catalysts and the reaction mechanism for hydrogenation are also discussed.

Abstract Image

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

钼催化的均相氢化反应：催化剂设计、活化模式和反应机理方面的最新创新

人们日益认识到，过渡金属催化的反应在相对温和的条件下进行，因此在合成有机化学中至关重要。在这方面，钼（Mo）配合物因其丰富的氧化还原活性、丰度和低毒性而被视为一类极具吸引力的催化剂。近年来，钼催化技术取得了重大进展，为活化 E-H 键带来了多种有用的转化。本章将重点介绍钼催化在氢化反应方面的最新进展。此外，还讨论了钼基催化剂的合成和氢化反应机理。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文去求助

来源期刊

Journal of Catalysis 工程技术-工程：化工

CiteScore

12.30

自引率

5.50%

发文量

447

审稿时长

31 days

期刊介绍： The Journal of Catalysis publishes scholarly articles on both heterogeneous and homogeneous catalysis, covering a wide range of chemical transformations. These include various types of catalysis, such as those mediated by photons, plasmons, and electrons. The focus of the studies is to understand the relationship between catalytic function and the underlying chemical properties of surfaces and metal complexes. The articles in the journal offer innovative concepts and explore the synthesis and kinetics of inorganic solids and homogeneous complexes. Furthermore, they discuss spectroscopic techniques for characterizing catalysts, investigate the interaction of probes and reacting species with catalysts, and employ theoretical methods. The research presented in the journal should have direct relevance to the field of catalytic processes, addressing either fundamental aspects or applications of catalysis.

期刊最新文献

Editorial Board Contents continued Graphical abstract TOC Graphical abstract TOC Direct synthesis of amides from nitroarenes and carboxylic acids via CO-mediated reduction