Enhancing EMI Shielding Efficiency of Polyurethane Foam by Incorporating MWCNT-Decorated Hollow Glass Microspheres.

IF 4.3 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY ACS Omega Pub Date : 2025-01-10 eCollection Date: 2025-01-21 DOI:10.1021/acsomega.4c10167
Salma Sultana, Mostafizur Rahaman, Mohammed Rehaan Chandan
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Abstract

This work explores the enhancement of EMI shielding efficiency of polyurethane (PU) foam by loading multiwall carbon nanotube (MWCNTs)-decorated hollow glass microspheres (HGMs). MWCNT was coated onto the HGM surface by a simple solution casting technique. The coated HGM particles were loaded in PU foams, resulting in an even dispersion of MWCNT in the foam struts, thereby forming an interconnected conductive network in the polymer matrix. The synthesized polymeric foam composites were characterized for bulk density, cellular morphology, Fourier transform infrared spectra, compression strength, electrical conductivity, and EMI shielding efficiency. The highest electrical conductivity, i.e., 15.75 × 10-3 S/cm, was achieved at 13 wt % loading, which resulted in the EMI shielding efficiency of -25.03 dB. Finally, we proposed a mechanism exploring the enhancement of EMI shielding of PU foam composite showing that the incident EMI radiations are being absorbed into the material due to the presence of interconnected MWCNTs and successive reflection via hollow glass spheres. The synthesized foam can be used as an EMI shielding material in such applications where flexibility and lightweight are the primary requirements.

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通过加入经 MWCNT 装饰的中空玻璃微球提高聚氨酯泡沫的 EMI 屏蔽效率。
本研究探讨了通过加载多壁碳纳米管(MWCNTs)装饰的中空玻璃微球(HGMs)来增强聚氨酯(PU)泡沫的电磁干扰屏蔽效率。采用简单的溶液铸造技术将MWCNT包覆在HGM表面。包覆的HGM颗粒被加载到PU泡沫中,导致MWCNT均匀分散在泡沫支柱中,从而在聚合物基体中形成相互连接的导电网络。对合成的聚合物泡沫复合材料进行了体积密度、细胞形态、傅里叶变换红外光谱、抗压强度、电导率和电磁干扰屏蔽效率的表征。在负载为13.wt %时,达到了最高的电导率,即15.75 × 10-3 S/cm,这导致EMI屏蔽效率为-25.03 dB。最后,我们提出了一种探索PU泡沫复合材料增强EMI屏蔽的机制,表明由于相互连接的MWCNTs的存在和通过空心玻璃球的连续反射,入射的EMI辐射被吸收到材料中。合成泡沫可以用作电磁干扰屏蔽材料,在这些应用中,灵活性和轻量化是主要要求。
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来源期刊
ACS Omega
ACS Omega Chemical Engineering-General Chemical Engineering
CiteScore
6.60
自引率
4.90%
发文量
3945
审稿时长
2.4 months
期刊介绍: ACS Omega is an open-access global publication for scientific articles that describe new findings in chemistry and interfacing areas of science, without any perceived evaluation of immediate impact.
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