Synthesis of SnO₂/COF green nanomaterials for effective pesticide decomposition and promoting tomato plants growth.

Abstract

In last few decades, the agriculture sector is facing various type of crops diseases originated by crop pests. Among various crops the tomato plant is greatly affected by many pests such as aphids and whiteflies, which are badly decreasing tomato plant yield and effecting its growth. In last few years, various type of pesticides such as Neonicotinoids and Pyrethroids are employed with are badly effecting eco system and water bodies. In this research work, we prepared SnO2 nanosheets (SONS) by in-situ and green synthesis approach. Remarkably, SONS exhibit a larger surface area, tailored pore size, and higher catalytic performance than SnO2 nanoparticles (SONP). To further improve the efficiency of SONS, we coupled it with covalent organic farmwork nanosheets (COFNS) via the hydrothermal approach. The SONS@COFNS hybrid nanocatalysts exhibit improved carrier migration, enhanced porosity, multiple active sites, and exceptional light absorption capabilities. The as prepared green nanomaterials delivered improved activities for Neonicotinoids and Pyrethroids degradation. Remarkably, the most active sample 6COFNS/SONS showed the highest degradation efficiency (94%), which is approximately 1.92 times higher than the degradation efficiency of pristine SONS (49%). This work will ultimately contribute to developing green, ecofriendly nanomaterials for pesticides degradation and promoting tomato plants growth.