A sulfonated and nitrated polyether ether ketone/polyvinyl chloride modified atmosphere packaging delays the deterioration of grapes.

IF 3.3 2区农林科学 Q1 AGRICULTURE, MULTIDISCIPLINARY Journal of the Science of Food and Agriculture Pub Date : 2025-01-27 DOI:10.1002/jsfa.14124

Xianhui Tang, Yuting Huang, Liang Zhu

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引用次数: 0

Abstract

Background: Polyether ether ketone (PEEK) was modified by a sulfuric and nitric acid mixed system to improve the solubility of the material and the gas selective permeability of the film. SN1 and SN5, synthesized from mixed acid systems (with ratios of nitric acid and sulfuric acid of 1:1 and 1:5, respectively) were chosen because they had comparable nitro groups but differing sulfonyl groups. To investigate the impact of the type and content of sulfonated and nitrated polyether ether ketone (SNPEEK) on the structure and physicochemical properties of the films, SN1/polyvinyl chloride (PVC) and SN5/polyvinyl chloride films were made by adding varying amounts of SN1 and SN5 (0.5%, 1.0%, 1.5%, 2.0% and 2.5 wt%), respectively.

Results: SNPEEK (with ratios of nitric acid and sulfuric acid of 1:1-9) with high nitric acid group concentration outperformed nitrated polyether ether ketone (NPEEK) (with ratios of nitric acid and sulfuric acid of 3-9:1) with a low nitric acid concentration in terms of solubility at room temperature and expanded the application range. The inclusion of SNPEEK resulted in more micropores on the membrane microstructure, and higher contents of -SO₃H and -NO₂ groups enhanced the polarity, which improved permeability and selectivity for CO₂ and O₂ and the moisture permeability of the membranes. During grape storage (4 ± 1 °C), 1.0% SN1/PVC and 1.0% SN5/PVC membranes reached equilibrium gas concentration on day 4 (4.6-5.4% CO₂, 17.6-18.1% O₂; 3.5-4.1% CO₂ and 18.6-19.1% O₂), grapes showed lower electrolyte leakage as well as higher hardness, total soluble solid content and vitamin C content.

Conclusion: Because there are few studies on modified PEEK air conditioning packaging for grape preservation, SNPEEK/PVC membrane has practical value. In the present study, 1.0% SN1/PVC and 1.0% SN5/PVC membranes extended the shelf life by more than 16 and 8 days, respectively, compared to the blank group (unsealed packaging). © 2025 Society of Chemical Industry.

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来源期刊

Journal of the Science of Food and Agriculture 工程技术-农业综合

CiteScore

8.10

自引率

4.90%

发文量

634

审稿时长

3.1 months

期刊介绍： The Journal of the Science of Food and Agriculture publishes peer-reviewed original research, reviews, mini-reviews, perspectives and spotlights in these areas, with particular emphasis on interdisciplinary studies at the agriculture/ food interface. Published for SCI by John Wiley & Sons Ltd. SCI (Society of Chemical Industry) is a unique international forum where science meets business on independent, impartial ground. Anyone can join and current Members include consumers, business people, environmentalists, industrialists, farmers, and researchers. The Society offers a chance to share information between sectors as diverse as food and agriculture, pharmaceuticals, biotechnology, materials, chemicals, environmental science and safety. As well as organising educational events, SCI awards a number of prestigious honours and scholarships each year, publishes peer-reviewed journals, and provides Members with news from their sectors in the respected magazine, Chemistry & Industry . Originally established in London in 1881 and in New York in 1894, SCI is a registered charity with Members in over 70 countries.