Effect of B2O3/SiO2 ratio on photoluminescence properties and stability of red-emitting CsPb(Br/I)3 borosilicate quantum dots glass

IF 5.8 2区 材料科学 Q2 CHEMISTRY, PHYSICAL Journal of Alloys and Compounds Pub Date : 2025-01-30 DOI:10.1016/j.jallcom.2025.178925
Keyi Gu, Yongmin Duan, Shugang Li, Ying Tian, Juan Du, Junjie Zhang
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引用次数: 0

Abstract

In recent years, inorganic perovskite quantum dots (PQDs) have garnered significant attention, but the photoluminescence (PL) properties and stability of red-emitting PQDs need to be further enhanced. In this work, the precipitation of CsPb(Br/I)3 quantum dots into borosilicate glass was effectively enabled by the high-temperature melt-quenching method. With the B2O3/SiO2 ratio increased, the glass network structure gradually loosened, which enhanced the precipitation of PQDs. Simultaneously, the PL intensity of CsPb(Br/I)3 PQDs glass increased, with a near twentyfold rise in the photoluminescence quantum yield (PLQY). The variable temperature test of PQDs glass shows that PQDs glass has good thermal stability. Finally, a red-emitting LED and a WLED were prepared by using the prepared red-emitting CsPb(Br/I)3 PQDs glass. This paper serves as a reference for incorporating red-emitting CsPb(Br/I)3 PQDs glass into WLED development.
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来源期刊
Journal of Alloys and Compounds
Journal of Alloys and Compounds 工程技术-材料科学:综合
CiteScore
11.10
自引率
14.50%
发文量
5146
审稿时长
67 days
期刊介绍: The Journal of Alloys and Compounds is intended to serve as an international medium for the publication of work on solid materials comprising compounds as well as alloys. Its great strength lies in the diversity of discipline which it encompasses, drawing together results from materials science, solid-state chemistry and physics.
期刊最新文献
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