{"title":"Palladium-Catalyzed Catellani-Type Selective C-H Silylation of Aryl-TT salts","authors":"Ziyao Tang, Mangang Guan, Tianqiang Wang, Guojun Yu, Jiaze Qin, Jingfeng Lan, Rulong Yan","doi":"10.1039/d4qo02349h","DOIUrl":null,"url":null,"abstract":"A palladium-catalyzed three-component reaction of aryl-thianthrenium salts, norbornene/diphenylacetylene, and hexamethyldisilane has been developed for the assembly of highly functionalized disilanes, in which two C-Si bonds and one C-C bond are constructed. Meanwhile, various functional groups are tolerated and the desired products are obtained in moderate to high yields.","PeriodicalId":97,"journal":{"name":"Organic Chemistry Frontiers","volume":"15 1","pages":""},"PeriodicalIF":4.6000,"publicationDate":"2025-01-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Organic Chemistry Frontiers","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4qo02349h","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
引用次数: 0
Abstract
A palladium-catalyzed three-component reaction of aryl-thianthrenium salts, norbornene/diphenylacetylene, and hexamethyldisilane has been developed for the assembly of highly functionalized disilanes, in which two C-Si bonds and one C-C bond are constructed. Meanwhile, various functional groups are tolerated and the desired products are obtained in moderate to high yields.
期刊介绍：
Organic Chemistry Frontiers is an esteemed journal that publishes high-quality research across the field of organic chemistry. It places a significant emphasis on studies that contribute substantially to the field by introducing new or significantly improved protocols and methodologies. The journal covers a wide array of topics which include, but are not limited to, organic synthesis, the development of synthetic methodologies, catalysis, natural products, functional organic materials, supramolecular and macromolecular chemistry, as well as physical and computational organic chemistry.
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