Lingli Liu , Yangian Cheng , Changduo Pan , Jin-Tao Yu
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引用次数: 0
Abstract
A Heck-type alkylation of enamides with N-trifluoroethyl hydroxylamine reagents was developed under photocatalytic conditions. This stereoselective reaction provides amido-substituted (E)-α-trifluoromethyl allylamines in yields up to 96%. In the mechanism, photoredox-induced 1,2-H shift of the in situ generated N-trifluoroethyl radical was involved.
期刊介绍：
Organic & Biomolecular Chemistry is an international journal using integrated research in chemistry-organic chemistry. Founded in 2003 by the Royal Society of Chemistry, the journal is published in Semimonthly issues and has been indexed by SCIE, a leading international database. The journal focuses on the key research and cutting-edge progress in the field of chemistry-organic chemistry, publishes and reports the research results in this field in a timely manner, and is committed to becoming a window and platform for rapid academic exchanges among peers in this field. The journal's impact factor in 2023 is 2.9, and its CiteScore is 5.5.
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