Study on the Mechanism of Facet Formation Based on the Shape of Temperature Field

IF 3.4 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Crystal Growth & Design Pub Date : 2025-01-05 DOI:10.1021/acs.cgd.4c01438
Hongyu Shao, Xixi Xiong, Xianglong Yang*, Desheng Wang, Laibin Zhao, Zhenxing Fu, Wenhao Han, Guojie Hu, Xiaomeng Li, Xuejian Xie, Guojian Yu, Xiufang Chen*, Xiaobo Hu and Xiangang Xu, 
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Abstract

This paper presents a systematic study of the facet formation on the wafer surface at the end of large-diameter 4H-SiC crystal growth, guided by numerical simulations. The influence of different temperature field shapes on facet position and shape was examined through resistivity tests and wafer scanning. Various models were developed to explain these effects, with facet shape changes ultimately interpreted through thermodynamic principles. Facets were found to form when the basal plane is tangent to the growth interface. The convexity K is directly proportional to the position P of the facet from the edge. The appearance of double facets on the same side due to large convexity K1, confirms that the temperature field shape is a critical factor in determining the facet position. The facet shape can be viewed as a cross-section formed by the intersection of the basal plane and the growth interface. The length of the facet H is inversely related to the crystal convexity K. Both the width of the facet D and the inner angle θ are significantly influenced by the convexity K1. As the convexity K1 increases, the inner angle θ decreases, while the width D increases.

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基于温度场形状的小面形成机理研究
本文以数值模拟为指导,系统研究了大直径4H-SiC晶体生长末端晶圆表面的小面形成。通过电阻率测试和晶圆扫描,研究了不同温度场形状对晶面位置和形状的影响。各种模型被开发来解释这些影响,facet形状的变化最终通过热力学原理来解释。发现当基面与生长界面相切时形成刻面。凸度K与面距边的位置P成正比。由于大凸度K1,在同一侧出现双晶面,证实了温度场形状是决定晶面位置的关键因素。面形可以看作是基面与生长界面相交形成的横截面。晶面宽度H与晶面凸度k成反比,晶面宽度D和晶面内角θ均受晶面凸度K1的显著影响。随着凸度K1的增大,内角θ减小,宽度D增大。
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来源期刊
Crystal Growth & Design
Crystal Growth & Design 化学-材料科学:综合
CiteScore
6.30
自引率
10.50%
发文量
650
审稿时长
1.9 months
期刊介绍: The aim of Crystal Growth & Design is to stimulate crossfertilization of knowledge among scientists and engineers working in the fields of crystal growth, crystal engineering, and the industrial application of crystalline materials. Crystal Growth & Design publishes theoretical and experimental studies of the physical, chemical, and biological phenomena and processes related to the design, growth, and application of crystalline materials. Synergistic approaches originating from different disciplines and technologies and integrating the fields of crystal growth, crystal engineering, intermolecular interactions, and industrial application are encouraged.
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