L. V. Panova, D. A. Lemenovskii, M. I. Afanasov, M. A. Popkov, R. O. Burlutsky, M. M. Brusova, V. N. Talanova, D. N. Kholodkov
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引用次数: 0
Abstract
An efficient method has been developed for the synthesis of siloxane aerogels with a hybrid structure built into the polymer structure. At the initial stage, a gel was obtained by polycondensation of tetraethoxysilane and ferrocene-containing alkoxysilanes, catalyzed by BF3 ⋅ Et2O in acetone. The transformation of gels into aerogels was performed using supercritical carbon dioxide (SC-CO2). The aerogel samples were characterized in detail by Mössbauer spectroscopy and nitrogen adsorption methods, and the density of the materials was determined. The iron content in the resulting aerogels varied from 3.6 to 8.7 wt % (or 11.9–28.7 wt % ferrocene units).
期刊介绍：
Russian Journal of Physical Chemistry B: Focus on Physics is a journal that publishes studies in the following areas: elementary physical and chemical processes; structure of chemical compounds, reactivity, effect of external field and environment on chemical transformations; molecular dynamics and molecular organization; dynamics and kinetics of photoand radiation-induced processes; mechanism of chemical reactions in gas and condensed phases and at interfaces; chain and thermal processes of ignition, combustion and detonation in gases, two-phase and condensed systems; shock waves; new physical methods of examining chemical reactions; and biological processes in chemical physics.
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