{"title":"A new copper complex of lysine on mesoporous KIT-6 as a robust and homoselective catalyst in the synthesis of tetrazoles","authors":"Elham Mohseni, Arash Ghorbani‑Choghamarani, Bahman Tahmasbi, Masoomeh Norouzi, Manzar Akbari","doi":"10.1007/s10934-024-01696-4","DOIUrl":null,"url":null,"abstract":"<div><p>This study focuses on the synthesis of mesoporous KIT-6, followed by surface modification using lysine to facilitate metal complexation. A copper complex was then immobilized on the surface of the modified KIT-6 (Cu-lysine@KIT-6). The Cu-lysine@KIT-6 material was subsequently characterized using various techniques, including AAS, BET, SEM, EDS, WDX, XRD, FTIR, and TGA. After characterization, the catalytic performance of Cu-lysine@KIT-6 was evaluated in the homoselective synthesis of tetrazole derivatives. Significantly, the Cu-lysine@KIT-6 catalyst demonstrates recoverability and reusability without significant loss of catalytic activity.</p></div>","PeriodicalId":660,"journal":{"name":"Journal of Porous Materials","volume":"32 1","pages":"289 - 299"},"PeriodicalIF":2.5000,"publicationDate":"2024-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Porous Materials","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s10934-024-01696-4","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
引用次数: 0
Abstract
This study focuses on the synthesis of mesoporous KIT-6, followed by surface modification using lysine to facilitate metal complexation. A copper complex was then immobilized on the surface of the modified KIT-6 (Cu-lysine@KIT-6). The Cu-lysine@KIT-6 material was subsequently characterized using various techniques, including AAS, BET, SEM, EDS, WDX, XRD, FTIR, and TGA. After characterization, the catalytic performance of Cu-lysine@KIT-6 was evaluated in the homoselective synthesis of tetrazole derivatives. Significantly, the Cu-lysine@KIT-6 catalyst demonstrates recoverability and reusability without significant loss of catalytic activity.
期刊介绍：
The Journal of Porous Materials is an interdisciplinary and international periodical devoted to all types of porous materials. Its aim is the rapid publication
of high quality, peer-reviewed papers focused on the synthesis, processing, characterization and property evaluation of all porous materials. The objective is to
establish a unique journal that will serve as a principal means of communication for the growing interdisciplinary field of porous materials.
Porous materials include microporous materials with 50 nm pores.
Examples of microporous materials are natural and synthetic molecular sieves, cationic and anionic clays, pillared clays, tobermorites, pillared Zr and Ti
phosphates, spherosilicates, carbons, porous polymers, xerogels, etc. Mesoporous materials include synthetic molecular sieves, xerogels, aerogels, glasses, glass
ceramics, porous polymers, etc.; while macroporous materials include ceramics, glass ceramics, porous polymers, aerogels, cement, etc. The porous materials
can be crystalline, semicrystalline or noncrystalline, or combinations thereof. They can also be either organic, inorganic, or their composites. The overall
objective of the journal is the establishment of one main forum covering the basic and applied aspects of all porous materials.
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