{"title":"Catalytic Bond-Forming Reactions Using Aluminium(III)","authors":"Dipanjana Choudhury, Dominic S. Wright","doi":"10.1002/ejic.202400638","DOIUrl":null,"url":null,"abstract":"<p>Static catalysis using neutral and cationic Al(III) complexes, in which the oxidation state of the metal does not change, can be applied to a range of catalytic bond-forming reactions which have similar characteristics to transition metal analogues. This short review (although not intended to be comprehensive) highlights the current state of development in the areas of dehydrocoupling, alkene polymerisation, and other bond forming reactions involving single-site Al(III) catalysts, focusing in particular on the key factors involved in molecular activation and the mechanisms of catalysis.</p>","PeriodicalId":38,"journal":{"name":"European Journal of Inorganic Chemistry","volume":"28 3","pages":""},"PeriodicalIF":2.2000,"publicationDate":"2024-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ejic.202400638","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"European Journal of Inorganic Chemistry","FirstCategoryId":"1","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ejic.202400638","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
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Abstract
Static catalysis using neutral and cationic Al(III) complexes, in which the oxidation state of the metal does not change, can be applied to a range of catalytic bond-forming reactions which have similar characteristics to transition metal analogues. This short review (although not intended to be comprehensive) highlights the current state of development in the areas of dehydrocoupling, alkene polymerisation, and other bond forming reactions involving single-site Al(III) catalysts, focusing in particular on the key factors involved in molecular activation and the mechanisms of catalysis.
期刊介绍：
The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies.
The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry:
Chemische Berichte
Bulletin des Sociétés Chimiques Belges
Bulletin de la Société Chimique de France
Gazzetta Chimica Italiana
Recueil des Travaux Chimiques des Pays-Bas
Anales de Química
Chimika Chronika
Revista Portuguesa de Química
ACH—Models in Chemistry
Polish Journal of Chemistry
The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.
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