Hugo Marchi Luciano, Ricard López-Coll, Rubén Álvarez-Yebra, Agustí Lledó
{"title":"A superior and accessible cavitand receptor for the binding of monoterpenes and sesquiterpenes in water.","authors":"Hugo Marchi Luciano, Ricard López-Coll, Rubén Álvarez-Yebra, Agustí Lledó","doi":"10.1039/d5qo00161g","DOIUrl":null,"url":null,"abstract":"A water-soluble receptor based on resorcin[4]arene featuring 8 solubilising carboxylate units (BC4) has been obtained in a straightforward manner without chromatographic purifications. BC4 is soluble in water in a wide range of pH, and is able to accommodate guests of different sizes and shapes, including monoterpenes and sesquiterpenes, providing and enhanced binding capabilities with respect to previously reported analogues. The molecular recognition events within BC4 are sensitive to subtle changes in guest shape and size, as illustrated by disparate exchange kinetics observed among the guests tested.","PeriodicalId":97,"journal":{"name":"Organic Chemistry Frontiers","volume":"61 1","pages":""},"PeriodicalIF":4.6000,"publicationDate":"2025-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Organic Chemistry Frontiers","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d5qo00161g","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
引用次数: 0
Abstract
A water-soluble receptor based on resorcin[4]arene featuring 8 solubilising carboxylate units (BC4) has been obtained in a straightforward manner without chromatographic purifications. BC4 is soluble in water in a wide range of pH, and is able to accommodate guests of different sizes and shapes, including monoterpenes and sesquiterpenes, providing and enhanced binding capabilities with respect to previously reported analogues. The molecular recognition events within BC4 are sensitive to subtle changes in guest shape and size, as illustrated by disparate exchange kinetics observed among the guests tested.
期刊介绍：
Organic Chemistry Frontiers is an esteemed journal that publishes high-quality research across the field of organic chemistry. It places a significant emphasis on studies that contribute substantially to the field by introducing new or significantly improved protocols and methodologies. The journal covers a wide array of topics which include, but are not limited to, organic synthesis, the development of synthetic methodologies, catalysis, natural products, functional organic materials, supramolecular and macromolecular chemistry, as well as physical and computational organic chemistry.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
