{"title":"C–H Arylation of Aminoquinones through Electrochemical Denitrogenative Coupling","authors":"Yeliang Xue, Shaozhong Wang","doi":"10.1021/acs.joc.4c02909","DOIUrl":null,"url":null,"abstract":"An electrooxidative C–C coupling between arylhydrazines and aminoquinones has been developed for the construction of aryl-substituted aminoquinones, which features excellent chemo- and regioselectivity. Mechanistic studies support the idea that the denitrogenative formation of aryl radicals might be involved in the metal-free C–H arylation.","PeriodicalId":57,"journal":{"name":"Journal of Organic Chemistry","volume":"55 1","pages":""},"PeriodicalIF":3.6000,"publicationDate":"2025-02-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Organic Chemistry","FirstCategoryId":"1","ListUrlMain":"https://doi.org/10.1021/acs.joc.4c02909","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
引用次数: 0
Abstract
An electrooxidative C–C coupling between arylhydrazines and aminoquinones has been developed for the construction of aryl-substituted aminoquinones, which features excellent chemo- and regioselectivity. Mechanistic studies support the idea that the denitrogenative formation of aryl radicals might be involved in the metal-free C–H arylation.
期刊介绍：
Journal of Organic Chemistry welcomes original contributions of fundamental research in all branches of the theory and practice of organic chemistry. In selecting manuscripts for publication, the editors place emphasis on the quality and novelty of the work, as well as the breadth of interest to the organic chemistry community.
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