Numerical simulation of space charge transport properties of polypropylene laminated paper

IF 3 3区 化学 Q3 CHEMISTRY, PHYSICAL Computational and Theoretical Chemistry Pub Date : 2025-03-01 Epub Date: 2025-01-20 DOI:10.1016/j.comptc.2025.115089
Xi Chen, Minghan Li, Rui Li, Junyi Ma, Tianyan Jiang, Maoqiang Bi
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Abstract

Polypropylene laminated paper (PPLP) serves as an exemplary insulation material for high-temperature superconducting direct current (DC) cables. However, the accumulation of internal space charge can distort the local electric field intensity, leading to material degradation. Currently, the majority of space charge transport analyses for PPLP rely on experimental measurements, with its microscopic processes necessitating further exploration. This paper delves into the interaction and evolution processes among various microscopic particles through numerical simulation. Adopting the bipolar carrier model, we analyze the impacts of temperature, mobility, trap density, and trap energy level on the space charge distribution within PPLP by integrating the interface charge theory and trap theory of multilayer dielectrics. Our findings reveal that as temperature decreases, the space charge injection effect diminishes and stabilizes after reaching a certain threshold. Lower mobility results in charge accumulation at the corresponding electrode, causing electric field distortion and a more pronounced damaging effect, whereas charge accumulation in the middle region is less significant, leading to lesser damage. Furthermore, lower trap levels and densities result in weaker charge accumulation, with charges migrating more towards the opposite electrode, thus exhibiting heteropolar charge accumulation at the electrodes.

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聚丙烯层压纸空间电荷输运特性的数值模拟
聚丙烯层压纸(PPLP)是高温超导直流(DC)电缆的典型绝缘材料。然而,内部空间电荷的积累会扭曲局部电场强度,导致材料降解。目前,PPLP的空间电荷输运分析大多依赖于实验测量,其微观过程有待进一步探索。本文通过数值模拟研究了各种微观粒子之间的相互作用和演化过程。采用双极载流子模型,结合界面电荷理论和多层介质的陷阱理论,分析了温度、迁移率、陷阱密度和陷阱能级对PPLP内部空间电荷分布的影响。结果表明,随着温度的降低,空间电荷注入效应逐渐减弱,并在达到一定阈值后趋于稳定。较低的迁移率导致相应电极的电荷积累,导致电场畸变和更明显的破坏效应,而中间区域的电荷积累不那么显著,导致较小的损伤。此外,较低的陷阱水平和密度导致较弱的电荷积累,电荷更多地向相反的电极迁移,从而在电极上表现出异极性电荷积累。
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来源期刊
CiteScore
4.20
自引率
10.70%
发文量
331
审稿时长
31 days
期刊介绍: Computational and Theoretical Chemistry publishes high quality, original reports of significance in computational and theoretical chemistry including those that deal with problems of structure, properties, energetics, weak interactions, reaction mechanisms, catalysis, and reaction rates involving atoms, molecules, clusters, surfaces, and bulk matter.
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