Uncovering the interface slipping and microplastic accumulation mechanism of carbon nanotube fibers under different temperatures

IF 11.6 2区 材料科学 Q1 CHEMISTRY, PHYSICAL Carbon Pub Date : 2025-02-01 Epub Date: 2024-12-05 DOI:10.1016/j.carbon.2024.119898
Pengfei Wang , Deya Wang , Yangfan Wu , Ziqing Zhou , Jie Tian , Gengzhi Sun , Songlin Xu
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Abstract

Understanding the microplastic accumulation behavior of advanced carbon nanotube (CNT) fibers under complex thermal conditions is crucial in aerospace structures' durability and safety design, and the intrinsic plastic mechanism of CNT fibers under high-temperature prospects further investigation from the theoretical to the experimental. Herein, a novel CNT-CNT interface model was developed to clarify the microplastic evolution mechanism and its temperature effect. A series of cyclic-loading experiments at different temperatures were investigated to uncover the plastic accumulation process of CNT fibers. The in-situ scanning electric microscopy (SEM) experiments were introduced to observe the microstructure evolution of the CNT fiber under cyclic loading. The CNT fibers show more serious plasticity and weaker high-temperature fatigue resistance. The distance and overlap length between CNTs dominate the evolution of materials' plastic and thermal behavior. It can be concluded that optimizing the arrangement of the microstructures and limiting the thermal expansion between tubes will improve the fatigue resistance of CNT fibers. This work could provide an in-depth description of microplastic mechanisms and better guidance for the aerospace application of high-performance fibers under complex loading environments.

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揭示了不同温度下碳纳米管纤维的界面滑移和微塑性积累机理
了解先进碳纳米管(CNT)纤维在复杂热条件下的微塑性积累行为对航空航天结构的耐久性和安全性设计至关重要,并进一步从理论到实验研究CNT纤维在高温条件下的内在塑性机理。为此,建立了一种新的碳纳米管-碳纳米管界面模型,以阐明微塑性演化机制及其温度效应。通过不同温度下的循环加载实验,揭示了碳纳米管纤维的塑性积累过程。采用原位扫描电镜(SEM)实验,观察了碳纳米管纤维在循环载荷作用下的微观结构演变。碳纳米管纤维的塑性较差,耐高温疲劳性能较差。CNTs之间的距离和重叠长度决定了材料塑性和热行为的演变。结果表明,优化碳纳米管的微观结构和限制管间热膨胀可以提高碳纳米管纤维的抗疲劳性能。该研究可为微塑性机理的深入描述和高性能纤维在复杂载荷环境下的航空应用提供更好的指导。
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来源期刊
Carbon
Carbon 工程技术-材料科学:综合
CiteScore
20.80
自引率
7.30%
发文量
0
审稿时长
23 days
期刊介绍: The journal Carbon is an international multidisciplinary forum for communicating scientific advances in the field of carbon materials. It reports new findings related to the formation, structure, properties, behaviors, and technological applications of carbons. Carbons are a broad class of ordered or disordered solid phases composed primarily of elemental carbon, including but not limited to carbon black, carbon fibers and filaments, carbon nanotubes, diamond and diamond-like carbon, fullerenes, glassy carbon, graphite, graphene, graphene-oxide, porous carbons, pyrolytic carbon, and other sp2 and non-sp2 hybridized carbon systems. Carbon is the companion title to the open access journal Carbon Trends. Relevant application areas for carbon materials include biology and medicine, catalysis, electronic, optoelectronic, spintronic, high-frequency, and photonic devices, energy storage and conversion systems, environmental applications and water treatment, smart materials and systems, and structural and thermal applications.
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