Yihan Shan , Anwei Wang , Sifan Zhang , Deqin Liang , Mingyang He , Weiyou Zhou
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引用次数: 0
Abstract
An efficient and convenient catalytic system has been reported for the aerobic oxidation of alkylarenes based on Mn2Al layered double oxide (Mn2Al-LDO) without any additives. The heterogeneous catalytic system could tolerate various alkylarenes with satisfactory yields. The results demonstrated that Mn species in Mn2Al-LDO are the catalytically active sites, and both HAT (hydrogen atom transfer) and ET/PT (electron transfer/proton transfer) processes were suggested to be ascribed for the transformation. A possible reaction mechanism has been proposed based on a series of control experiments.
期刊介绍：
Tetrahedron Letters provides maximum dissemination of outstanding developments in organic chemistry. The journal is published weekly and covers developments in techniques, structures, methods and conclusions in experimental and theoretical organic chemistry. Rapid publication of timely and significant research results enables researchers from all over the world to transmit quickly their new contributions to large, international audiences.
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