Effect of pyrolysis temperature on the physical and chemical characteristics of pine wood biochar

Berhane Handiso , Timo Pääkkönen , Benjamin P. Wilson
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Abstract

Biochar is a useful bioproduct with a wide range of promising applications. The main objective of this study is to investigate the effect of pyrolysis temperatures on the physicochemical properties of biochar produced from pine wood using a slow pyrolysis methodology. Fourier transfer infrared (FTIR) spectroscopy analysis uncovered that the biochar synthesized at the different temperatures selected possessed distinct functional groups. The elemental analysis confirmed that an increase in pyrolysis temperature led to a rise in the carbon (C) concentration, whereas conversely there is a reciprocal decrease in the levels of oxygen (O) and hydrogen (H). Consequently, biochar produced at high temperatures showed low (O/C) and (H/C) fractions. Surface area (gas adsorption) studies indicated that the biochar surface area and pore volume increase at higher pyrolysis temperature. In contrast, the pore size was found to decrease at high temperatures. It was found that increased pyrolysis temperature resulted in reduced biochar yield. Biochar for use in specific applications like as an adsorbent material is ultimately influenced by the pyrolysis temperature. Therefore, it can be concluded that the results of the current study enhances the understanding on the effect of pyrolysis temperature on biochar synthesis and how different parameters can be used to tailor the material characteristics for specific applications.

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热解温度对松木生物炭理化特性的影响
生物炭是一种有用的生物产品,具有广泛的应用前景。本研究的主要目的是研究热解温度对松木慢速热解法制备生物炭理化性质的影响。傅里叶转移红外(FTIR)光谱分析发现,在不同温度合成的生物炭具有不同的官能团。元素分析证实,热解温度升高导致碳(C)浓度升高,反之,氧(O)和氢(H)浓度则呈负相关降低,因此,高温下生产的生物炭表现出较低的(O/C)和(H/C)分数。比表面积(气体吸附)研究表明,热解温度越高,生物炭的比表面积和孔隙体积越大。相反,在高温下发现孔隙尺寸减小。发现热解温度升高导致生物炭产率降低。作为吸附剂材料等特定应用的生物炭最终受到热解温度的影响。因此,可以得出结论,本研究结果增强了对热解温度对生物炭合成的影响的理解,以及如何使用不同的参数来定制特定应用的材料特性。
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