The effect of proton irradiation on dealloying of Alloy 800 in an aqueous environment

IF 3.2 2区 工程技术 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Journal of Nuclear Materials Pub Date : 2025-02-01 Epub Date: 2024-11-30 DOI:10.1016/j.jnucmat.2024.155554
M. Rezvanian, H. Gholamzadeh, K. Daub, F. Long, M.R. Daymond, S.Y. Persaud
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Abstract

The effect of prior proton irradiation on the subsequent corrosion and dealloying of Alloy 800 was investigated in a 50 wt. % NaOH caustic solution at 140 °C. Dealloying of irradiated (1 dpa) and non-irradiated Alloy 800 was characterized at the nanoscale to provide mechanistic insight. A porous surface film enriched in Ni was formed on both irradiated and non-irradiated materials due to selective dissolution of Fe and Cr. However, the microstructure and chemistry in the dealloyed layer was altered by irradiation, including deeper dealloyed layer penetration, finer porosity, and changes in the classical core-shell ligament structure in the irradiated material.
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质子辐照对800合金在水环境中合金化的影响
在50 wt. % NaOH烧碱溶液中,在140℃下研究了质子辐照对800合金后续腐蚀和脱合金的影响。在纳米尺度上对辐照(1dpa)和未辐照的800合金的脱合金化进行了表征,以提供机理。由于Fe和Cr的选择性溶解,辐照和未辐照材料表面都形成了富Ni的多孔膜。然而,辐照改变了合金层的微观结构和化学性质,包括更深的合金层穿透,更细的孔隙率,以及辐照材料经典的核-壳韧带结构的变化。
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来源期刊
Journal of Nuclear Materials
Journal of Nuclear Materials 工程技术-材料科学:综合
CiteScore
5.70
自引率
25.80%
发文量
601
审稿时长
63 days
期刊介绍: The Journal of Nuclear Materials publishes high quality papers in materials research for nuclear applications, primarily fission reactors, fusion reactors, and similar environments including radiation areas of charged particle accelerators. Both original research and critical review papers covering experimental, theoretical, and computational aspects of either fundamental or applied nature are welcome. The breadth of the field is such that a wide range of processes and properties in the field of materials science and engineering is of interest to the readership, spanning atom-scale processes, microstructures, thermodynamics, mechanical properties, physical properties, and corrosion, for example. Topics covered by JNM Fission reactor materials, including fuels, cladding, core structures, pressure vessels, coolant interactions with materials, moderator and control components, fission product behavior. Materials aspects of the entire fuel cycle. Materials aspects of the actinides and their compounds. Performance of nuclear waste materials; materials aspects of the immobilization of wastes. Fusion reactor materials, including first walls, blankets, insulators and magnets. Neutron and charged particle radiation effects in materials, including defects, transmutations, microstructures, phase changes and macroscopic properties. Interaction of plasmas, ion beams, electron beams and electromagnetic radiation with materials relevant to nuclear systems.
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