Characterization of palm pyrolysis oil produced from fresh palm fruit bunches with a modified downdraft biomass gasifier and burner as heat source

IF 6.2 2区 化学 Q1 CHEMISTRY, ANALYTICAL Journal of Analytical and Applied Pyrolysis Pub Date : 2025-03-01 Epub Date: 2024-12-16 DOI:10.1016/j.jaap.2024.106917
Nathawat Unsomsri , Sommas Kaewluan , Sittinun Tawkaew , Songkran Wiriyasart
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Abstract

Thailand relies heavily on crude oil imports, emphasizing the need for alternative, locally sourced energy solutions. This study highlights pyrolysis as a cost-effective method for converting biomass into energy and producing three primary outputs: pyrolysis oil, pyrolysis gas, and biochar. Fresh palm fruit bunches (FFB) from the Tenera strain were investigated as a feedstock for pyrolysis using a modified downdraft biomass gasifier and burner as heat sources. The FFB underwent size reduction to ensure a diameter of no more than 20 mm before pyrolysis. A 120-liter batch pyrolyzer was designed to maximize thermal efficiency and product yield. Key parameters, including pyrolysis temperatures of 400, 500, and 600 °C, were systematically analyzed. The highest yield of pyrolysis oil (24.66 %) was obtained at 400 °C, with chemical analysis identifying compounds such as naphthalene, heptadecanol, phenol, and methyl palmitate. Environmental evaluations showed significant reductions in greenhouse gas emissions, with 5.37 kg-CO2/kg-PPO less than LPG and 8.44 kg-CO2/kg-PPO less than electricity. This study demonstrates the feasibility of utilizing FFB for biofuel production and presents a sustainable framework for addressing energy demands in Thailand.
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采用改进的下吸式生物质气化炉和燃烧器作为热源,对新鲜棕榈果束制备的棕榈热解油进行表征
泰国严重依赖原油进口,强调需要替代的本地能源解决方案。本研究强调热解是一种将生物质转化为能源的经济有效的方法,并产生三种主要产出:热解油、热解气和生物炭。研究了来自Tenera菌株的新鲜棕榈果束(FFB)作为原料,使用改进的下吸式生物质气化炉和燃烧器作为热源进行热解。热解前对FFB进行了尺寸减小,以确保其直径不大于20 mm。设计了120升间歇式热解器,以最大限度地提高热效率和产品收率。对热解温度400、500、600 ℃等关键参数进行了系统分析。在400 °C时,热解油的收率最高(24.66 %),化学分析鉴定出萘、十六醇、苯酚和棕榈酸甲酯等化合物。环境评估显示,温室气体排放量显著减少,比液化石油气减少5.37 kg-CO2/kg-PPO,比电力减少8.44 kg-CO2/kg-PPO。本研究证明了利用FFB生产生物燃料的可行性,并提出了解决泰国能源需求的可持续框架。
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来源期刊
CiteScore
9.10
自引率
11.70%
发文量
340
审稿时长
44 days
期刊介绍: The Journal of Analytical and Applied Pyrolysis (JAAP) is devoted to the publication of papers dealing with innovative applications of pyrolysis processes, the characterization of products related to pyrolysis reactions, and investigations of reaction mechanism. To be considered by JAAP, a manuscript should present significant progress in these topics. The novelty must be satisfactorily argued in the cover letter. A manuscript with a cover letter to the editor not addressing the novelty is likely to be rejected without review.
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