From lead–acid batteries to perovskite solar cells – efficient recycling of Pb-containing materials†

IF 4.9 RSC sustainability Pub Date : 2025-01-16 DOI:10.1039/D4SU00470A
Jiajia Suo, Bowen Yang, Sonja Prideaux, Henrik Pettersson and Lars Kloo
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Abstract

The most efficient and stable perovskite solar cells typically contain lead compounds as a key component in the light-absorbing layer. To advance the commercialization of perovskite photovoltaics, it is crucial to address sustainability concerns regarding the use of toxic lead. In this work, we have developed a straightforward lead recycling pathway that converts lead compounds from lead–acid batteries into lead iodide. Purity analyses of the resulting lead iodide and the direct fabrication of perovskite solar cells demonstrate that the recycled lead iodide matches the quality of commercially available products. Most importantly, establishing this efficient lead recycling process not only supports sustainable recycling and resource utilization in a circular materials flow but also promotes the future development of perovskite photovoltaics.

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从铅酸电池到钙钛矿太阳能电池——含铅材料的高效回收†
最有效和稳定的钙钛矿太阳能电池通常含有铅化合物,作为光吸收层的关键成分。为了推进钙钛矿光伏发电的商业化,解决有关使用有毒铅的可持续性问题至关重要。在这项工作中,我们开发了一种直接的铅回收途径,将铅酸电池中的铅化合物转化为碘化铅。对所得碘化铅的纯度分析和钙钛矿太阳能电池的直接制造表明,回收的碘化铅符合市售产品的质量。最重要的是,建立这种高效的铅回收工艺不仅支持循环材料流中的可持续回收和资源利用,而且还促进了钙钛矿光伏电池的未来发展。
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