Polina I. Kudina, Anna S. Lisovenko, Mariya A. Kryukova, Igor V. Kazakov
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引用次数: 0
Abstract
The obtained results reveal simple synthetic approach for bidentate boron Lewis acids with the -OB(C6F5)2 acid group and aliphatic or aromatic linkers. Computational results showed comparable FIA for the -OB(C6F5)2 site in boron bidentate Lewis acids relative to initial B(C6F5)3. The relative Lewis acid strength of R[OB(C6F5)2]2 (R=C2H4, p-C6H4, m-C6H4) was characterized by Gutman-Beckett tests. The elimination of pentafluorobenzene by the reaction of R-OH with B(C6F5)3 can be used for the synthesis of R-OB(C6F5)2 derivatives and polydentate strong Lewis acids.
期刊介绍：
The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies.
The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry:
Chemische Berichte
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Gazzetta Chimica Italiana
Recueil des Travaux Chimiques des Pays-Bas
Anales de Química
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ACH—Models in Chemistry
Polish Journal of Chemistry
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