Dr. Felix Lindl, Dr. Torsten Thiess, Dr. James T. Goettel, Dr. Simon Dotzauer, Dr. Moritz Johannes Ernst, Prof. Dr. Guillaume Bélanger-Chabot, Prof. Dr. Holger Braunschweig
{"title":"Borole Ring Expansion Reactions with Boron Azides: A Versatile Pathway to Borylated Azaborinines","authors":"Dr. Felix Lindl, Dr. Torsten Thiess, Dr. James T. Goettel, Dr. Simon Dotzauer, Dr. Moritz Johannes Ernst, Prof. Dr. Guillaume Bélanger-Chabot, Prof. Dr. Holger Braunschweig","doi":"10.1002/ejic.202400498","DOIUrl":null,"url":null,"abstract":"<p>The reaction of boroles with organic azides is known to straightforwardly yield 1,2-azaborinines, which have generated significant interest as benzene bioisosteres. We show that this powerful synthetic pattern extends to a variety of structurally and chemically diverse boron azides, including recently reported diborane(4) azides. This provides a general, powerful borylation method to expand the chemistry of 1,2-azaborinines.</p>","PeriodicalId":38,"journal":{"name":"European Journal of Inorganic Chemistry","volume":"27 36","pages":""},"PeriodicalIF":2.2000,"publicationDate":"2024-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ejic.202400498","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"European Journal of Inorganic Chemistry","FirstCategoryId":"1","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ejic.202400498","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
The reaction of boroles with organic azides is known to straightforwardly yield 1,2-azaborinines, which have generated significant interest as benzene bioisosteres. We show that this powerful synthetic pattern extends to a variety of structurally and chemically diverse boron azides, including recently reported diborane(4) azides. This provides a general, powerful borylation method to expand the chemistry of 1,2-azaborinines.
期刊介绍：
The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies.
The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry:
Chemische Berichte
Bulletin des Sociétés Chimiques Belges
Bulletin de la Société Chimique de France
Gazzetta Chimica Italiana
Recueil des Travaux Chimiques des Pays-Bas
Anales de Química
Chimika Chronika
Revista Portuguesa de Química
ACH—Models in Chemistry
Polish Journal of Chemistry
The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
