Egg derived porous carbon decorated with Fe3O4 nanorods for high efficiency electromagnetic wave absorption

IF 11.6 2区 材料科学 Q1 CHEMISTRY, PHYSICAL Carbon Pub Date : 2025-03-10 Epub Date: 2025-01-31 DOI:10.1016/j.carbon.2025.120076
Yukun Miao , Meng Zhang , Quanxiu Liu , Tao Xi , Yong Liu , Yinyun Wang , Chang Wang , Anguo Cui , Zhongning Tian , Ting Wang , Jinyuan Liu , Qianqian Jia , Di Lan , YiCheng Bi , Zhenjiang Li
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Abstract

In this work, EDC@Fe3O4 nanocomposite wave-absorbing materials were obtained by using egg as a precursor and SiO2 templates to prepare porous structures of egg-derived carbon, followed by a simple reflow calcination process. The microwave absorption properties show that the magnetic content enhances the magnetic loss of the composite material, while the abundant defects and voids on the surface of the egg-derived porous carbon form a network that extends the transmission path of the electromagnetic wave. The synergistic effect of Fe3O4 and the porous carbon optimizes the impedance matching of the material and improves its attenuation ability. As a result, the EDC@Fe3O4 nanocomposites exhibit excellent microwave absorption properties. The best sample at 9.12 GHz with the strongest reflection loss (RLmin) of −54.19 dB at a matched thickness of 2.46 mm, and the best effective absorption bandwidth (EAB) value of 5.68 GHz at a matched thickness of 2.03 mm. In this study, a biomass-based porous carbon nanocomposite with lightweight, thin thickness, wide bandwidth, and high absorption capacity is designed and prepared by novel strategies, and EDC@Fe3O4 nanocomposites are shown to have excellent microwave absorptive properties. magnetic composites with light weight, thin thickness, wide bandwidth and strong absorption ability, and elucidated the synergistic electromagnetic loss mechanism of EDC@Fe3O4 nanocomposites.

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以Fe3O4纳米棒装饰的鸡蛋衍生多孔碳用于高效电磁波吸收
本文以鸡蛋为前驱体,以SiO2为模板制备鸡蛋衍生碳的多孔结构,然后进行简单的回流煅烧工艺,获得EDC@Fe3O4纳米复合吸波材料。微波吸收性能表明,磁性含量增加了复合材料的磁损耗,而蛋源多孔碳表面丰富的缺陷和空隙形成了一个网络,延长了电磁波的传输路径。Fe3O4与多孔碳的协同作用优化了材料的阻抗匹配,提高了材料的衰减能力。结果表明,EDC@Fe3O4纳米复合材料具有优异的微波吸收性能。在9.12 GHz的匹配厚度为2.46 mm时,样品的最大反射损耗(RLmin)为−54.19 dB;在匹配厚度为2.03 mm时,样品的最佳有效吸收带宽(EAB)值为5.68 GHz。在本研究中,采用新颖的策略设计并制备了轻质、薄厚度、宽带宽和高吸收容量的生物质基多孔碳纳米复合材料,EDC@Fe3O4纳米复合材料具有优异的微波吸收性能。研究了重量轻、厚度薄、带宽宽、吸收能力强的磁性复合材料,阐明了EDC@Fe3O4纳米复合材料的协同电磁损耗机理。
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来源期刊
Carbon
Carbon 工程技术-材料科学:综合
CiteScore
20.80
自引率
7.30%
发文量
0
审稿时长
23 days
期刊介绍: The journal Carbon is an international multidisciplinary forum for communicating scientific advances in the field of carbon materials. It reports new findings related to the formation, structure, properties, behaviors, and technological applications of carbons. Carbons are a broad class of ordered or disordered solid phases composed primarily of elemental carbon, including but not limited to carbon black, carbon fibers and filaments, carbon nanotubes, diamond and diamond-like carbon, fullerenes, glassy carbon, graphite, graphene, graphene-oxide, porous carbons, pyrolytic carbon, and other sp2 and non-sp2 hybridized carbon systems. Carbon is the companion title to the open access journal Carbon Trends. Relevant application areas for carbon materials include biology and medicine, catalysis, electronic, optoelectronic, spintronic, high-frequency, and photonic devices, energy storage and conversion systems, environmental applications and water treatment, smart materials and systems, and structural and thermal applications.
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