Double-layer coated Csf/SiC composite fabricated by LPBF/LSI with improved mechanical properties through fiber damage prevention and crack propagation inhibition

IF 6.2 2区 材料科学 Q1 MATERIALS SCIENCE, CERAMICS Journal of The European Ceramic Society Pub Date : 2025-07-01 Epub Date: 2025-01-29 DOI:10.1016/j.jeurceramsoc.2025.117248
Ce Sun , Song Zhang , Zimian Xu , Junchao He , Lihong Wu , Dongsheng Gu , Meijun Yang , Peng Chen , Xiao Han , Lixia Yang , Kai Liu , Yusheng Shi
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Abstract

The Csf/SiC composites are fabricated by Laser powder bed fusion/liquid silicon infiltration (LPBF/LSI). To prevent the Csf from being eroded by molten Si, and optimize the interface between the fiber and matrix, a pyrolytic carbon-silicon carbide (PyC-SiC) double-coated layer is synthesized on the surface of Csf. The SiC layer prevents the diffusion of molten Si, thereby shielding fibers from erosion. The PyC layer can form a weak bonding interface between the matrix and fibers, facilitating fiber extraction at crack tips during material fracture. The double-layer coating's dual action mechanism of fiber damage prevention and crack propagation inhibition significantly enhances the strength and fracture toughness of Csf/SiC composites. Csf/SiC composites with double-layer coated fibers exhibit a maximum bending strength of 257.11 MPa and a maximum fracture toughness of 3.60 MPa·m1/2, marking respective improvements of 8.51 % and 16.12 % compared to the Csf/SiC composites with original fibers.
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LPBF/LSI制备的双层涂层Csf/SiC复合材料通过防止纤维损伤和抑制裂纹扩展改善了力学性能
采用激光粉末床熔融/液态硅渗透(LPBF/LSI)法制备了Csf/SiC复合材料。为了防止Csf被熔融Si侵蚀,并优化纤维与基体之间的界面,在Csf表面合成了热解碳-碳化硅(PyC-SiC)双包覆层。碳化硅层防止熔融硅的扩散,从而保护纤维免受侵蚀。PyC层可以在基体和纤维之间形成弱结合界面,有利于材料断裂时裂纹尖端的纤维提取。双层涂层防止纤维损伤和抑制裂纹扩展的双重作用机制显著提高了Csf/SiC复合材料的强度和断裂韧性。双层包覆纤维的Csf/SiC复合材料的最大抗弯强度为257.11 MPa,最大断裂韧性为3.60 MPa·m1/2,分别比原纤维的Csf/SiC复合材料提高8.51 %和16.12 %。
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来源期刊
Journal of The European Ceramic Society
Journal of The European Ceramic Society 工程技术-材料科学:硅酸盐
CiteScore
10.70
自引率
12.30%
发文量
863
审稿时长
35 days
期刊介绍: The Journal of the European Ceramic Society publishes the results of original research and reviews relating to ceramic materials. Papers of either an experimental or theoretical character will be welcomed on a fully international basis. The emphasis is on novel generic science concerning the relationships between processing, microstructure and properties of polycrystalline ceramics consolidated at high temperature. Papers may relate to any of the conventional categories of ceramic: structural, functional, traditional or composite. The central objective is to sustain a high standard of research quality by means of appropriate reviewing procedures.
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