{"title":"Cp2ZrCl2-Catalyzed 2-Aluminoethylalumination of Aminomethyl Allenes with Triethylaluminum","authors":"T. P. Zosim, R. N. Kadikova, I. R. Ramazanov","doi":"10.1134/S1070428024120261","DOIUrl":null,"url":null,"abstract":"<p>It was shown for the first time that the Cp<sub>2</sub>ZrCl<sub>2</sub>-catalyzed reaction of dialkylaminomethyl allenes (<i>N</i>,<i>N</i>-dialkylbuta-2,3-dien-1-amines) with triethylaluminum results in regio- and stereoselective formation of (<i>Z</i>)-<i>N</i>,<i>N</i>-dialkylhex-2-en-1-amines. A probable reaction mechanism has been proposed.</p>","PeriodicalId":766,"journal":{"name":"Russian Journal of Organic Chemistry","volume":"60 12","pages":"2508 - 2511"},"PeriodicalIF":0.8000,"publicationDate":"2025-02-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Organic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1070428024120261","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
引用次数: 0
Abstract
It was shown for the first time that the Cp2ZrCl2-catalyzed reaction of dialkylaminomethyl allenes (N,N-dialkylbuta-2,3-dien-1-amines) with triethylaluminum results in regio- and stereoselective formation of (Z)-N,N-dialkylhex-2-en-1-amines. A probable reaction mechanism has been proposed.
期刊介绍：
Russian Journal of Organic Chemistry is an international peer reviewed journal that covers all aspects of modern organic chemistry including organic synthesis, theoretical organic chemistry, structure and mechanism, and the application of organometallic compounds in organic synthesis.
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