Biochar Derived from Waste Momordica Cochinchinensis Seed Shell as High-Performance Supercapacitor Electrodes

IF 5.5 3区 材料科学 Q2 CHEMISTRY, PHYSICAL ACS Applied Energy Materials Pub Date : 2025-01-24 DOI:10.1021/acsaem.4c02581
Yuzhu Shi, Juanqin Xue, Yongqi Yu, Guangdong Wu and Changbin Tang*, 
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Abstract

For the purpose of making high-value use of Chinese medicine waste, the preparation of derived biochar was studied and used as an electrode for supercapacitors (SCs). High-temperature KOH activation was used to convert the seed shells of discarded traditional Chinese medicine (Mubiezi) into graded porous carbon electrode materials, and the optimal electrode (MCSSAC-3) was obtained by optimizing the KOH addition ratio in this work. The MCSSAC-3 electrode obtained has a high specific surface area (1288.55 m2 g–1) and significantly higher specific capacitance of 302.29 F g–1 at 0.5 A g–1. The MCSSAC-3//MCSSAC-3 symmetric device has a high energy density of 11.13 Wh kg–1 at a power density of 350 W kg–1. In addition, even after 10,000 consecutive cycles, the MCSSAC-3//MCSSAC-3 symmetric device exhibits ideal capacitance retention of 87.16% at 10 A g–1. This work offers an approach for the preparation of low-cost and high-performance SCs carbon-based electrodes from discarded traditional Chinese medicine.

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废苦瓜籽壳生物炭制备高性能超级电容器电极
为实现中药废弃物的高价值利用,研究了衍生生物炭的制备,并将其作为超级电容器的电极。采用高温KOH活化法,将废弃中药种壳(木别子)转化为梯度多孔碳电极材料,并通过优化KOH添加比获得最佳电极(MCSSAC-3)。所获得的MCSSAC-3电极具有较高的比表面积(1288.55 m2 g-1)和更高的比电容,在0.5 a g-1时达到302.29 F - 1。MCSSAC-3//MCSSAC-3对称器件在350w kg-1的功率密度下具有11.13 Wh kg-1的高能量密度。此外,即使在连续10,000次循环后,MCSSAC-3//MCSSAC-3对称器件在10 A g-1下仍保持87.16%的理想电容。本研究为利用废弃中药制备低成本、高性能的SCs碳基电极提供了一条途径。
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来源期刊
ACS Applied Energy Materials
ACS Applied Energy Materials Materials Science-Materials Chemistry
CiteScore
10.30
自引率
6.20%
发文量
1368
期刊介绍: ACS Applied Energy Materials is an interdisciplinary journal publishing original research covering all aspects of materials, engineering, chemistry, physics and biology relevant to energy conversion and storage. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important energy applications.
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