{"title":"Designed Synthesis of Covalent Organic Multicycles","authors":"Tong Yang, Qian Gao, Xue-Hui Liu, Jin-Min Wu, Wei Wang, San-Yuan Ding","doi":"10.1021/jacs.4c16320","DOIUrl":null,"url":null,"abstract":"Covalent organic multicycles (COMs) have been designed and synthesized via the covalent assembly of rigid three-arm Y-shaped and U-shaped building blocks. These COMs have a precise tricyclic structure and exhibit remarkable solubility in a range of common solvents. Featuring well-defined cavities with electron-rich structures, these COMs displayed good adsorption capabilities for iodine in both its vapor and liquid states. Moreover, the solution processability allows for the facile fabrication of these COMs as uniform films on different substrates via the spin coating methods.","PeriodicalId":49,"journal":{"name":"Journal of the American Chemical Society","volume":"21 1","pages":""},"PeriodicalIF":15.6000,"publicationDate":"2025-02-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the American Chemical Society","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1021/jacs.4c16320","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Covalent organic multicycles (COMs) have been designed and synthesized via the covalent assembly of rigid three-arm Y-shaped and U-shaped building blocks. These COMs have a precise tricyclic structure and exhibit remarkable solubility in a range of common solvents. Featuring well-defined cavities with electron-rich structures, these COMs displayed good adsorption capabilities for iodine in both its vapor and liquid states. Moreover, the solution processability allows for the facile fabrication of these COMs as uniform films on different substrates via the spin coating methods.
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The flagship journal of the American Chemical Society, known as the Journal of the American Chemical Society (JACS), has been a prestigious publication since its establishment in 1879. It holds a preeminent position in the field of chemistry and related interdisciplinary sciences. JACS is committed to disseminating cutting-edge research papers, covering a wide range of topics, and encompasses approximately 19,000 pages of Articles, Communications, and Perspectives annually. With a weekly publication frequency, JACS plays a vital role in advancing the field of chemistry by providing essential research.
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