An alkali and rare earth metal mixed cyanurate KLa2(C3N3O3)2Cl with large birefringence: Synthesis and characterization

IF 2.4 4区 物理与天体物理 Q3 PHYSICS, CONDENSED MATTER Solid State Communications Pub Date : 2025-04-01 Epub Date: 2025-02-05 DOI:10.1016/j.ssc.2025.115871
Nengxuan Wang , Xinyuan Zhang , Fei Liang , Zhanggui Hu , Yicheng Wu
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Abstract

The indispensable and significant uses of optoelectronic functional materials in many sectors, including high-precision micro-processing, optical communications, and information storage, have garnered increasing attention. Combining alkali and rare-earth metals with π-conjugated (C3N3O3)3- groups can achieve large birefringence and short cut-off edges. A metal cyanurate, KLa2(C3N3O3)2Cl (KLCYC), has been successfully synthesized in the high-temperature condition. It crystallizes in the Hexagonal P63/m space group and features two-dimensional layers composed of (C3N3O3)3- and [LaO6Cl] polyhedral. KLCYC exhibits significant birefringence (Δncal = 0.316 at 1064 nm) and a wide band gap (Eg) around 5.0 eV. Theoretical calculations reveal that the optical properties are mainly due to planar π-conjugated (C3N3O3)3- groups.
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大双折射碱稀土混合氰尿酸盐KLa2(C3N3O3)2Cl的合成与表征
光电功能材料在高精度微加工、光通信、信息存储等领域的重要应用日益受到人们的关注。碱金属和稀土金属与π共轭(C3N3O3)3-基团结合可获得大双折射和短截止边。在高温条件下成功合成了金属氰尿酸盐KLCYC (C3N3O3)。它在六边形P63/m空间群中结晶,具有由(C3N3O3)3-和[la6cl]多面体组成的二维层。KLCYC具有显著的双折射特性(Δncal = 0.316在1064 nm处)和5.0 eV左右的宽带隙(Eg)。理论计算表明,π共轭(C3N3O3)3-基团的存在是影响其光学性质的主要原因。
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阿拉丁
KCNO
阿拉丁
LaCl3
来源期刊
Solid State Communications
Solid State Communications 物理-物理:凝聚态物理
CiteScore
3.40
自引率
4.80%
发文量
287
审稿时长
51 days
期刊介绍: Solid State Communications is an international medium for the publication of short communications and original research articles on significant developments in condensed matter science, giving scientists immediate access to important, recently completed work. The journal publishes original experimental and theoretical research on the physical and chemical properties of solids and other condensed systems and also on their preparation. The submission of manuscripts reporting research on the basic physics of materials science and devices, as well as of state-of-the-art microstructures and nanostructures, is encouraged. A coherent quantitative treatment emphasizing new physics is expected rather than a simple accumulation of experimental data. Consistent with these aims, the short communications should be kept concise and short, usually not longer than six printed pages. The number of figures and tables should also be kept to a minimum. Solid State Communications now also welcomes original research articles without length restrictions. The Fast-Track section of Solid State Communications is the venue for very rapid publication of short communications on significant developments in condensed matter science. The goal is to offer the broad condensed matter community quick and immediate access to publish recently completed papers in research areas that are rapidly evolving and in which there are developments with great potential impact.
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