Characterization of linear quadrupoles operated with amplitude-asymmetric sinusoidal waveforms.

IF 0.8 4区 化学 Q4 PHYSICS, ATOMIC, MOLECULAR & CHEMICAL European Journal of Mass Spectrometry Pub Date : 2025-02-01 Epub Date: 2025-02-10 DOI:10.1177/14690667251315048
Alexander I Ivanov, Alexey A Sysoev, Andrew N Konenkov, Nikolai V Konenkov
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Abstract

The stability regions formed by the asymmetric sinusoidal shape of the periodic supply potential of the quadrupole mass filter are calculated, with the signal duty cycle d=0.5. Two cases are considered, when A1<A2 and A1>A2, where A1 and A2 are the amplitudes of the positive and negative parts of the sinusoid. Stability islands are revealed, where the QMF operation is possible by changing amplitude A2 without DC potential. For the values A1=1 and A2=0.8, the mass selected instability mode with a resolution of about 7000 is found. In this island, the potential well depth reaches its maximum along the Y coordinate. At the amplitudes A1=1 and A2=1.8-2.0, stability regions are formed, the operation in which allows reaching R0.5=2000. The results of the transmission and excitation contours modeling confirm the validity of the method for calculating the stability diagrams of a linear quadrupole with asymmetric sinusoidal waveform.

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用幅度不对称正弦波形操作的线性四极的特性。
计算了四极质量滤波器周期性供电电位的非对称正弦形状形成的稳定区域,其信号占空比d=0.5。考虑两种情况,当A1A2和A1>A2,其中A1和A2是正弦波的正负部分的振幅。稳定性岛被揭示出来,其中通过改变振幅A2而没有直流电位的QMF操作是可能的。当A1=1和A2=0.8时,质量选择的不稳定模式分辨率约为7000。在这个岛上,井的潜在深度沿Y坐标达到最大值。在振幅A1=1和A2=1.8-2.0处形成稳定区,其运算允许达到R0.5=2000。传输线和激振线的建模结果证实了该方法计算非对称正弦线性四极杆稳定性图的有效性。
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来源期刊
CiteScore
2.40
自引率
7.70%
发文量
16
审稿时长
>12 weeks
期刊介绍: JMS - European Journal of Mass Spectrometry, is a peer-reviewed journal, devoted to the publication of innovative research in mass spectrometry. Articles in the journal come from proteomics, metabolomics, petroleomics and other areas developing under the umbrella of the “omic revolution”.
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