Guo-Ling Zhao , Bo Kong , Zhi-Guo Wang , Xiu-Fang Mo , Xiao-Yi Yi
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引用次数: 0
Abstract
Treatment of pyrrole-cyclometalated IrIII starting [IrIII(K2C,N-dpp)(H)(Cl)(PPh3)2] (Hdpp = 2-[5-(pyridin-2-yl)-1H-pyrrol-2-yl]pyridine) and [IrIIICp*Cl2]2 in the presence of base affords binuclear IrIII–IrIII complex [IrIII (H)(Cl)(PPh3)2(μ-dpp)IrIIICp*(Cl)] (1). The structural analysis of 1 displays two IrIII centers are linked by dpp2− ligand with novel μ-(K2C,N,K2N′,N″) coordination mode. The catalytic performance of 1 for formic acid dehydrogenation in water and CO2 hydrogenation is explored.
期刊介绍：
Polyhedron publishes original, fundamental, experimental and theoretical work of the highest quality in all the major areas of inorganic chemistry. This includes synthetic chemistry, coordination chemistry, organometallic chemistry, bioinorganic chemistry, and solid-state and materials chemistry.
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