1,2,3-Benzotriazolate Cluster Complex (Bu4N)2[W6I8(N3C6H4)6]

IF 1.2 4区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR Journal of Structural Chemistry Pub Date : 2025-02-12 DOI:10.1134/S0022476625010081

M. A. Mikhaylov, A. S. Berezin, T. S. Sukhikh, D. G. Sheven’, N. B. Kompankov, M. N. Sokolov, K. A. Tagiltsev

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引用次数: 0

Abstract

New luminescent cluster complex (Bu₄N)₂[W₆I₈(N₃C₆H₄)₆] (I) is obtained by the reaction of (Bu₄N)₂[W₆I₈(OOCCH₃)₆] with 1-trimethylsilyl-1,2,3-benzotriazole (Me₃Si-N₃C₆H₄) is obtained. The crystal structure is determined for cocrystallizate I with 1,2,3-benzotriazole (Bu₄N)₂[W₆I₈(N₃C₆H₄)₆]· ·4(N₃C₆H₅) (I·4BTA). According to single crystal X-ray diffraction data, tungsten atoms of the {W₆I₈}⁴⁺ cluster core are monodentate coordinated by N1 atoms of 1,2,3-benzotriazolate ligands (average W–N distance 2.20 Å). For the powder sample of I bright phosphorescence is revealed with the emission maximum at 640 nm, φ = 24%, τ = 266 µs (in the air atmosphere). Complex I is characterized by electrospray mass spectrometry, proton magnetic resonance, C, H, N elemental analysis, and IR spectroscopy.

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来源期刊

Journal of Structural Chemistry 化学-无机化学与核化学

CiteScore

1.60

自引率

12.50%

发文量

142

审稿时长

8.3 months

期刊介绍： Journal is an interdisciplinary publication covering all aspects of structural chemistry, including the theory of molecular structure and chemical bond; the use of physical methods to study the electronic and spatial structure of chemical species; structural features of liquids, solutions, surfaces, supramolecular systems, nano- and solid materials; and the crystal structure of solids.