Influence of the Synthesis Temperature on the Structure and Properties of Highly Cr-Substituted Barium Hexaferrite

IF 1.4 4区 化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR Journal of Structural Chemistry Pub Date : 2025-02-12 DOI:10.1134/S0022476625010160
D. P. Sherstyuk, A. I. Kovalev, A. R. Zykova, V. E. Zhivulin, D. E. Zhivulin, D. A. Vinnik
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Abstract

Highly Cr-substituted barium hexaferrite (BaFe12–xCrxO19, x = 5, 6, 7) is prepared by the solid-phase synthesis at the isothermal temperatures of 1400 °C, 1500 °C, and 1600 °C. The optimal synthesis temperatures are determined from the obtained powder XRD and electron microscopy data. Correlations are established between chemical composition and synthesis temperature on the one hand and unit cell parameters, particle size, Curie temperature, and electrical resistivity on the other hand.

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合成温度对高cr取代六铁体钡结构和性能的影响
在1400℃、1500℃和1600℃等温固相合成条件下制备了高cr取代六铁体钡(BaFe12-xCrxO19, x = 5,6,7)。根据所得粉末XRD和电镜数据确定了最佳合成温度。建立了化学成分和合成温度与晶胞参数、粒径、居里温度和电阻率之间的相关性。
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来源期刊
Journal of Structural Chemistry
Journal of Structural Chemistry 化学-无机化学与核化学
CiteScore
1.60
自引率
12.50%
发文量
142
审稿时长
8.3 months
期刊介绍: Journal is an interdisciplinary publication covering all aspects of structural chemistry, including the theory of molecular structure and chemical bond; the use of physical methods to study the electronic and spatial structure of chemical species; structural features of liquids, solutions, surfaces, supramolecular systems, nano- and solid materials; and the crystal structure of solids.
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