Side Interactions in High-Temperature Mass Spectrometric Studies of Metal Oxides

IF 0.8 4区 化学 Q4 CHEMISTRY, PHYSICAL Russian Journal of Physical Chemistry A Pub Date : 2025-02-11 DOI:10.1134/S0036024424702832
N. A. Gribchenkova, A. S. Smirnov, A. S. Alikhanyan
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Abstract

Side interactions between the test substance and container were summarized and classified based on the experience of studying the thermodynamics of vaporization of metal oxides obtained by high-temperature or Knudsen effusion mass spectrometry (KEMS). The importance of identifying side interactions is emphasized and illustrated with examples. Practical experience in selecting the container material based on the available theoretical information and experimental testing is described.

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金属氧化物高温质谱研究中的侧相互作用
根据高温或Knudsen渗出质谱法(KEMS)研究金属氧化物汽化热力学的经验,总结和分类了被测物质与容器之间的侧相互作用。强调并举例说明识别侧相互作用的重要性。介绍了在现有理论资料和实验测试的基础上选择容器材料的实践经验。
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来源期刊
CiteScore
1.20
自引率
14.30%
发文量
376
审稿时长
5.1 months
期刊介绍: Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world. Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.
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