Ya. V. Nikolskiy, V. V. Emelyanov, E. L. Krasnykh, Yu. F. Ivanova, A. A. Ruslyakov
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引用次数: 0
Abstract
Gas–liquid chromatography on a non-polar phase is used in the 393.2–473.2 K range of temperatures to determine the retention characteristics and enthalpies of sorption for 10 esters of 2,2-dimethylbutyric acid and linear alcohols C1–C10. A linear dependence of the indices of retention on temperature and the number of carbon atoms in the alcohol molecule is shown for all studied ethers. Enthalpies of evaporation are calculated, and the excess enthalpies of the mixing of ethers are determined.
期刊介绍：
Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world.
Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.
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