Non-Monotonic Relaxation Processes in Ga95Nd5 and Ga97Sm3 Melts

IF 0.8 4区 化学 Q4 CHEMISTRY, PHYSICAL Russian Journal of Physical Chemistry A Pub Date : 2025-02-11 DOI:10.1134/S0036024424703023
A. I. Rusanova, L. D. Son, B. A. Rusanov, V. E. Sidorov, A. L. Beltyukov
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Abstract

Experimental studies of density and viscosity of gallium-rare-earth metal composition alloys with light lanthanides (neodymium and samarium) are investigated for the first time. It is established that these compositions are characterized by long-term non-monotonic changes of properties (relaxation processes) in liquid state. The coefficients of temperature expansion of Ga95Nd5 and Ga97Sm3 alloys and activation energy of viscous flows of their melts are calculated based on experimental data.

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Ga95Nd5 和 Ga97Sm3 熔体中的非单调弛豫过程
本文首次对含轻镧系元素(钕和钐)的镓-稀土金属复合合金的密度和粘度进行了实验研究。证实了这些组合物在液态下具有长期的非单调性质变化(弛豫过程)。根据实验数据计算了Ga95Nd5和Ga97Sm3合金的温膨胀系数和熔体黏性流动的活化能。
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来源期刊
CiteScore
1.20
自引率
14.30%
发文量
376
审稿时长
5.1 months
期刊介绍: Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world. Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.
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