Pore-Scale Investigation of Water-Alternating-Gas Injection for CCUS in Water-Wet Porous Media

IF 5.3 3区 工程技术 Q2 ENERGY & FUELS Energy & Fuels Pub Date : 2025-02-03 DOI:10.1021/acs.energyfuels.4c05679
Sheng Li, Yifan Zhang, Ningning Wang, Zhiheng Wang* and Haihu Liu*, 
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Abstract

Water-alternating-gas (WAG) injection is a promising technique for sequestering greenhouse gases and enhancing oil recovery. However, the pore-scale mass transport physics, carbon capture, utilization, and storage (CCUS) mechanisms, and optimization of WAG injection under reservoir conditions remain poorly understood. To fill this gap, we, by developing the graphics processing unit (GPU)-accelerated lattice Boltzmann method, conduct pore-scale simulations of WAG injection in a water-wet porous medium. Results reveal that in WAG injection, alternately injected water and gas sweep lower and upper regions of the porous medium, thus improving oil recovery compared to sole water flooding or gas injection. In particular, WAG injection that ends with gas injection exhibits significant potential for both enhanced oil recovery (EOR) and CO2 storage. For a fixed number of injection cycles, increasing individual slug size Iss leads to a higher oil recovery; however, when fixing the total injected volume for different Iss, a lower Iss favors the formation of more isolated clusters, which not only hinders the development of preferential flow paths but also decreases the water–gas density difference in the mixing region, thus increasing sweeping efficiency. The isolated and scattered distribution of CO2 reduces the risk of leakage, which is beneficial to CO2 storage. It is also found that the gravitational segregation effect becomes less pronounced with decreasing gravity, which ultimately leads to a higher oil recovery. In reduced gravity conditions, two typical capillary phenomena, namely, multiple displacement and double capillary trapping, are observed, and when the gravity vanishes, WAG injection leads to almost the same oil recovery as sole water flooding. Moreover, increasing the injection rate results in stronger mixing and interaction between injected gas and water, forming more isolated clusters and thus improving oil recovery.

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水湿多孔介质中水-气交替注CCUS的孔隙尺度研究
注水换气是一种很有前途的温室气体封存和提高采收率的技术。然而,孔隙尺度的质量输运物理、碳捕获、利用和储存(CCUS)机制以及储层条件下WAG注入的优化仍然知之甚少。为了填补这一空白,我们通过开发图形处理单元(GPU)加速的晶格玻尔兹曼方法,在水湿多孔介质中进行了WAG注入的孔隙尺度模拟。结果表明,与单纯水驱或注气相比,WAG交替注入水、气对孔隙介质下部和上部区域进行扫描,从而提高了采收率。特别是,在注气结束时注入WAG,在提高采收率(EOR)和二氧化碳储存方面具有巨大的潜力。对于固定数量的注入周期,增加单个段塞尺寸Iss可以提高采收率;然而,当固定不同Iss的总注入体积时,较低的Iss有利于形成更孤立的簇,这不仅阻碍了优先流道的发展,而且减小了混合区域的水气密度差,从而提高了清扫效率。CO2的隔离和分散分布降低了泄漏的风险,有利于CO2的储存。随着重力的减小,重力偏析效应逐渐减弱,最终提高了采收率。在低重力条件下,观察到两种典型的毛细现象,即多次驱替和双毛细圈闭,当重力消失时,注入WAG的采收率与单纯水驱几乎相同。此外,增加注入速度可以增强注入气与水之间的混合和相互作用,形成更隔离的簇,从而提高采收率。
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来源期刊
Energy & Fuels
Energy & Fuels 工程技术-工程:化工
CiteScore
9.20
自引率
13.20%
发文量
1101
审稿时长
2.1 months
期刊介绍: Energy & Fuels publishes reports of research in the technical area defined by the intersection of the disciplines of chemistry and chemical engineering and the application domain of non-nuclear energy and fuels. This includes research directed at the formation of, exploration for, and production of fossil fuels and biomass; the properties and structure or molecular composition of both raw fuels and refined products; the chemistry involved in the processing and utilization of fuels; fuel cells and their applications; and the analytical and instrumental techniques used in investigations of the foregoing areas.
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