Kinetics of thermal decomposition and hydrogen reduction of Cobalt compounds: A review

IF 3.5 2区 化学 Q2 CHEMISTRY, ANALYTICAL Thermochimica Acta Pub Date : 2025-02-06 DOI:10.1016/j.tca.2025.179952
Sonja Pöyhtäri , Eetu-Pekka Heikkinen , Anne Heikkilä
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Abstract

Cobalt is an important transition metal that plays a critical role in the growing battery industry, and in hard metal applications and super alloys. Cobalt powder can be produced via solid-state hydrogen reduction of different cobalt compounds from which cobalt oxides have been widely studied since 1960s. Hydrogen is an efficient and environmentally friendly reductant and its utilization in metal refining is being increasingly studied. This paper presents an overview of important findings regarding hydrogen reduction kinetics of cobalt oxides alongside thermal decomposition kinetics of cobalt carbonates and hydroxides. This will assist researchers in the future to choose and modify hydrogen reduction parameters by identifying the factors affecting the overall reduction reaction of different cobalt compounds and characteristics of derived cobalt products.
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钴化合物的热分解和氢还原动力学研究进展
钴是一种重要的过渡金属,在不断发展的电池工业、硬金属应用和超级合金中发挥着关键作用。钴粉可以通过固态氢还原不同的钴化合物来生产,钴氧化物自20世纪60年代以来得到了广泛的研究。氢是一种高效、环保的还原剂,其在金属精炼中的应用正受到越来越多的研究。本文概述了钴氧化物的氢还原动力学以及碳酸钴和氢氧化物的热分解动力学的重要发现。通过识别影响不同钴化合物整体还原反应的因素和衍生钴产物的特性,有助于今后研究人员选择和修改氢还原参数。
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来源期刊
Thermochimica Acta
Thermochimica Acta 化学-分析化学
CiteScore
6.50
自引率
8.60%
发文量
210
审稿时长
40 days
期刊介绍: Thermochimica Acta publishes original research contributions covering all aspects of thermoanalytical and calorimetric methods and their application to experimental chemistry, physics, biology and engineering. The journal aims to span the whole range from fundamental research to practical application. The journal focuses on the research that advances physical and analytical science of thermal phenomena. Therefore, the manuscripts are expected to provide important insights into the thermal phenomena studied or to propose significant improvements of analytical or computational techniques employed in thermal studies. Manuscripts that report the results of routine thermal measurements are not suitable for publication in Thermochimica Acta. The journal particularly welcomes papers from newly emerging areas as well as from the traditional strength areas: - New and improved instrumentation and methods - Thermal properties and behavior of materials - Kinetics of thermally stimulated processes
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