Design and fabrication of laser cladding pomegranate bionic structure FeCoNiCrAl high entropy alloy / AlN ceramic high temperature radar-infrared compatible hidden composite coating

IF 6.3 2区 材料科学 Q2 CHEMISTRY, PHYSICAL Journal of Alloys and Compounds Pub Date : 2025-03-05 Epub Date: 2025-02-13 DOI:10.1016/j.jallcom.2025.179166
Sanyang Gao , Xuming Pang , Sen Mu , Jibin Pu , Cheng Chen
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Abstract

With the advancement of multi-target detection technology, radar-wave-infrared-compatible stealth coatings have emerged as crucial materials. To overcome the challenges associated with poor radar-wave-infrared stealth performance in harsh high-temperature environments, FeCoNiCrAl/AlN composite coatings with pomegranate bionic structures were designed and fabricated by laser cladding. Laser-induced FeCoNiCrAl / AlN generates TiN phase in situ in the molten pool and drives TiN to tightly stack around AlN through Marangoni convection, thereby self-assembling to form an AlN-TiN core-shell structure. Modifying the FeCoNiCrAl/AlN mass ratio substantially influences the heterogeneous interfacial polarization between metal and ceramic phases, thereby effectively regulating the coating's electromagnetic (EM) wave response. When the FeCoNiCrAl/AlN mass ratio is optimized to 8:2, the coating demonstrates excellent high-temperature radar wave and infrared (IR) stealth compatibility. With a coating thickness of 2 mm, it achieves a reflection loss (RL) of −15.1 dB at 14.75 GHz and a IR emissivity of 0.28 in the 3–5μm range. The material maintains stable performance at elevated temperatures of 500°C and 700°C, with RL values of −11 dB and −10 dB, and IR emissivity of 0.33 and 0.328, respectively. The laser-induced melt convection-driven bionic structure FeCoNiCrAl / AlN coating has high radar wave absorption and low infrared emission, which can achieve tunable design integration and efficient preparation of high-temperature compatible stealth coatings.

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激光熔覆石榴仿生结构FeCoNiCrAl高熵合金/ AlN陶瓷高温雷达-红外兼容隐身复合涂层的设计与制备
随着多目标探测技术的进步,雷达波-红外兼容隐身涂料已成为关键的隐身材料。为了克服恶劣高温环境下雷达红外隐身性能差的挑战,采用激光熔覆的方法设计并制备了具有石榴仿生结构的FeCoNiCrAl/AlN复合涂层。激光诱导的FeCoNiCrAl / AlN在熔池中原位生成TiN相,并通过Marangoni对流驱动TiN在AlN周围紧密堆积,从而自组装形成AlN-TiN核壳结构。改变FeCoNiCrAl/AlN的质量比可以显著影响金属相和陶瓷相之间的非均相界面极化,从而有效调节涂层的电磁波响应。当FeCoNiCrAl/AlN质量比优化为8:2时,涂层具有良好的高温雷达波和红外隐身性能。当涂层厚度为2mm时,在14.75 GHz时的反射损耗(RL)为-15.1 dB,在3-5μm范围内的红外发射率为0.28。该材料在500°C和700°C高温下保持稳定的性能,RL值分别为-11 dB和-10 dB,红外发射率分别为0.33和0.328。激光诱导熔体对流驱动仿生结构FeCoNiCrAl / AlN涂层具有高雷达波吸收和低红外发射特性,可实现可调设计集成和高效制备高温兼容隐身涂层。
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来源期刊
Journal of Alloys and Compounds
Journal of Alloys and Compounds 工程技术-材料科学:综合
CiteScore
11.10
自引率
14.50%
发文量
5146
审稿时长
67 days
期刊介绍: The Journal of Alloys and Compounds is intended to serve as an international medium for the publication of work on solid materials comprising compounds as well as alloys. Its great strength lies in the diversity of discipline which it encompasses, drawing together results from materials science, solid-state chemistry and physics.
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