Synthesis of Hydrochars via Wet Torrefaction of Biomass for Sustainable Energy Production: A Life Cycle Assessment Study

IF 7.3 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY ACS Sustainable Chemistry & Engineering Pub Date : 2025-02-13 DOI:10.1021/acssuschemeng.4c09303
Frederick Jit Fook Phang, Jiuan Jing Chew, Swati Chakraborty, Jaka Sunarso
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Abstract

Wet torrefaction of biomass is an emerging technology for synthesizing hydrochars, which could be used as a replacement for conventional coal for energy generation. This study employs a “cradle-to-gate” approach to evaluate the environmental impacts of hydrochar synthesis via wet torrefaction in comparison to conventional fossil-based coal, focusing on an energy value of 10 MJ. The results indicate that the hydrochar synthesis process has a higher overall environmental impact than conventional coal, primarily due to the significant energy demands of wet torrefaction. However, the combustion of hydrochars yields a substantially lower environmental impact, achieving a climate change reduction of ∼93.70% compared to conventional coal, irrespective of whether levulinic acid was used as a catalyst. The environmental impact increases slightly with the addition of levulinic acid due to the resources required to produce levulinic acid. The benefits during combustion remain significant. A sensitivity analysis was conducted by replacing the energy source for wet torrefaction with renewable hydropower to assess the process sustainability further. This substitution resulted in remarkable reductions in climate change potential (global warming) and fossil fuel depletion, with decreases of 98.63% and 99.39%, respectively. Overall, these findings underscore the potential of hydrochars as an environmentally friendly replacement for conventional coal in energy generation, particularly when produced by using renewable energy sources.

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生物质湿法焙烧合成可持续能源烃类:生命周期评价研究
生物质湿法焙烧是一种新兴的合成碳氢化合物的技术,可以替代传统的煤炭发电。本研究采用“从摇篮到大门”的方法,以10兆焦耳的能值为重点,与传统的化石基煤相比,评估湿法焦合成对环境的影响。结果表明,水合物合成过程比常规煤具有更高的整体环境影响,主要是由于湿法焙烧的能源需求很大。然而,无论是否使用乙酰丙酸作为催化剂,与传统煤炭相比,碳氢化合物燃烧产生的环境影响要小得多,实现了气候变化减少约93.70%。由于生产乙酰丙酸所需的资源,添加乙酰丙酸对环境的影响略有增加。燃烧期间的好处仍然是显著的。通过用可再生水电替代湿法焙烧能源进行敏感性分析,进一步评估该工艺的可持续性。这种替代导致了气候变化潜力(全球变暖)和化石燃料消耗的显著降低,分别降低了98.63%和99.39%。总的来说,这些发现强调了碳氢化合物在能源生产中作为传统煤炭的环保替代品的潜力,特别是在使用可再生能源生产时。
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来源期刊
ACS Sustainable Chemistry & Engineering
ACS Sustainable Chemistry & Engineering CHEMISTRY, MULTIDISCIPLINARY-ENGINEERING, CHEMICAL
CiteScore
13.80
自引率
4.80%
发文量
1470
审稿时长
1.7 months
期刊介绍: ACS Sustainable Chemistry & Engineering is a prestigious weekly peer-reviewed scientific journal published by the American Chemical Society. Dedicated to advancing the principles of green chemistry and green engineering, it covers a wide array of research topics including green chemistry, green engineering, biomass, alternative energy, and life cycle assessment. The journal welcomes submissions in various formats, including Letters, Articles, Features, and Perspectives (Reviews), that address the challenges of sustainability in the chemical enterprise and contribute to the advancement of sustainable practices. Join us in shaping the future of sustainable chemistry and engineering.
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